TY - JOUR
T1 - 3D architectured zinc-chromium layered double hydroxide with nickel cobalt sulfide composite for the electrochemical detection of ronidazole
AU - Priya, Thangavelu Sakthi
AU - Chen, Tse Wei
AU - Chen, Shen Ming
AU - Kokulnathan, Thangavelu
AU - Lou, Bih Show
AU - Ullah, Riaz
AU - Al-Onazi, Wedad A.
AU - Elshikh, Mohamed S.
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024/4/9
Y1 - 2024/4/9
N2 - Currently, the elevated usage of antibiotics in the health sector has led to genetic modification, antibiotic resistance, and other adverse effects on ecosystems. Ronidazole (RZ) is a multifunctional veterinary drug that can cause severe health and environmental problems. Hence, it is essential to monitor this drug in environmental and biological samples with high accuracy. Analogously, we fabricated a zinc-chromium-layered double hydroxide with a nickel cobalt sulfide (ZC/NCS) catalyst for the electrochemical sensing of RZ. Its structural and morphological properties were deeply examined with several spectroscopic techniques. The electrochemical properties were investigated using impedance and voltammetric methods. The electroanalytical performance of ZC/NCS was studied with different voltammetric approaches. Based on the results, our prepared ZC/NCS demonstrated a low limit of detection (1.1 nM and 2.6 nM), satisfactory linear ranges of 0.01-297 μM (at low concentration), and 297-2187 μM (at high concentration), optimal sensitivity (0.374 μA μM−1 cm−2), and high performance. Furthermore, the designed sensor was applied to monitor RZ in environmental (river water), animal (chicken meat extract), and human (urine) samples, with remarkable recovery values (98.6-101.8%). Therefore, our prepared ZC/NCS composite is a promising electrode material for the real-time analysis of RZ.
AB - Currently, the elevated usage of antibiotics in the health sector has led to genetic modification, antibiotic resistance, and other adverse effects on ecosystems. Ronidazole (RZ) is a multifunctional veterinary drug that can cause severe health and environmental problems. Hence, it is essential to monitor this drug in environmental and biological samples with high accuracy. Analogously, we fabricated a zinc-chromium-layered double hydroxide with a nickel cobalt sulfide (ZC/NCS) catalyst for the electrochemical sensing of RZ. Its structural and morphological properties were deeply examined with several spectroscopic techniques. The electrochemical properties were investigated using impedance and voltammetric methods. The electroanalytical performance of ZC/NCS was studied with different voltammetric approaches. Based on the results, our prepared ZC/NCS demonstrated a low limit of detection (1.1 nM and 2.6 nM), satisfactory linear ranges of 0.01-297 μM (at low concentration), and 297-2187 μM (at high concentration), optimal sensitivity (0.374 μA μM−1 cm−2), and high performance. Furthermore, the designed sensor was applied to monitor RZ in environmental (river water), animal (chicken meat extract), and human (urine) samples, with remarkable recovery values (98.6-101.8%). Therefore, our prepared ZC/NCS composite is a promising electrode material for the real-time analysis of RZ.
UR - http://www.scopus.com/inward/record.url?scp=85192233297&partnerID=8YFLogxK
U2 - 10.1039/d3en00804e
DO - 10.1039/d3en00804e
M3 - 文章
AN - SCOPUS:85192233297
SN - 2051-8153
VL - 11
SP - 2021
EP - 2035
JO - Environmental Science: Nano
JF - Environmental Science: Nano
IS - 5
ER -
