A CZTSe solar cell with 8.2% power conversion efficiency fabricated using electrodeposited Cu/Sn/Zn precursor and a three-step selenization process at low Se pressure

Liyong Yao, Jianping Ao, Ming Jer Jeng*, Jinlian Bi, Shoushuai Gao, Guozhong Sun, Qing He, Zhiqiang Zhou, Yun Sun, Liann Be Chang

*Corresponding author for this work

Research output: Contribution to journalJournal Article peer-review

48 Scopus citations

Abstract

In preparing Cu2ZnSnSe4 (CZTSe) thin films, selenization at high Se pressure is likely to form a thick molybdenum diselenide (MoSe2) layer. An excessively thick MoSe2 layer degrades the performance of CZTSe solar cells. Annealing under low Se pressure has been suggested to prevent the formation of such a thick MoSe2 layer. However, the potential loss of Sn metal from CZTSe thin films at low Se pressure or high temperature raises the additional difficulty of controlling the compositions and phases of the films. Carefully controlling these selenization parameters to yield high-quality CZTSe thin films is important. This study investigates the loss of Sn and the formation of molybdenum diselenide in CZTSe thin films at low Se pressure. Three-step selenization at low Se pressure is performed on an electrodeposited Cu/Sn/Zn precursor to prepare high-quality CZTSe thin films. In the first step, rapid thermal annealing with a substrate temperature of 500 °C and a low Se vapor pressure of 4.6 Pa was performed to reduce the loss of Sn and the thickness of the MoSe2 layer, and thus to obtain a Cu-poor and Zn-rich film. In the second step, a high annealing temperature of 570 °C and an inert gas at high pressure was used to improve elemental diffusion and increase the uniformity of the elemental distribution. In the third step, thermal annealing with a substrate temperature of 500 °C and a low Se vapor pressure of 4.6 Pa was performed to reduce the loss of Sn and the thickness of the MoSe2 layer, and to eliminate the impurity phase of SnSe (which was formed in the second step of annealing) on the surface of the CZTS films. The loss of Sn and the formation of molybdenum diselenide in the CZTSe thin films are negligible when this three-step selenization at low Se pressure is used. When the selenization parameters are properly controlled, CZTSe solar cells with an efficiency of as high as 8.2% can be obtained.

Original languageEnglish
Pages (from-to)318-324
Number of pages7
JournalSolar Energy Materials and Solar Cells
Volume159
DOIs
StatePublished - 01 01 2017

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V.

Keywords

  • CuZnSnSe (CZTSe) thin films
  • Low Se vapor pressure
  • Molybdenum diselenide (MoSe)
  • The loss of Sn
  • Three-step selenization

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