A fast reversible equilibrium in the reaction of olefins with mercuric trifluoroacetate in aprotic solvents. Nature of the addition compounds

Herbert C. Brown; Min Hon Rei

doi:10.1039/C29690001296

A fast reversible equilibrium in the reaction of olefins with mercuric trifluoroacetate in aprotic solvents. Nature of the addition compounds

Herbert C. Brown^*
, Min Hon Rei

^*Corresponding author for this work

Richard B. Wetherill Laboratory

Research output: Contribution to journal › Journal Article › peer-review

26 Scopus citations

Abstract

In aprotic solvents such as tetrahydrofuran, olefins react rapidly and reversibly with mercuric trifluoroacetate to form addition compounds, in contrast to their behaviour with silver nitrate with which they form silver ion π-complexes.

Original language	English
Pages (from-to)	1296-1297
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Transactions
Issue number	22
DOIs	https://doi.org/10.1039/C29690001296
State	Published - 1969
Externally published	Yes

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title = "A fast reversible equilibrium in the reaction of olefins with mercuric trifluoroacetate in aprotic solvents. Nature of the addition compounds",

abstract = "In aprotic solvents such as tetrahydrofuran, olefins react rapidly and reversibly with mercuric trifluoroacetate to form addition compounds, in contrast to their behaviour with silver nitrate with which they form silver ion π-complexes.",

author = "Brown, \{Herbert C.\} and Rei, \{Min Hon\}",

year = "1969",

doi = "10.1039/C29690001296",

language = "英语",

pages = "1296--1297",

journal = "Journal of the Chemical Society, Chemical Transactions",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

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T1 - A fast reversible equilibrium in the reaction of olefins with mercuric trifluoroacetate in aprotic solvents. Nature of the addition compounds

AU - Brown, Herbert C.

AU - Rei, Min Hon

PY - 1969

Y1 - 1969

N2 - In aprotic solvents such as tetrahydrofuran, olefins react rapidly and reversibly with mercuric trifluoroacetate to form addition compounds, in contrast to their behaviour with silver nitrate with which they form silver ion π-complexes.

AB - In aprotic solvents such as tetrahydrofuran, olefins react rapidly and reversibly with mercuric trifluoroacetate to form addition compounds, in contrast to their behaviour with silver nitrate with which they form silver ion π-complexes.

UR - https://www.scopus.com/pages/publications/37049138427

U2 - 10.1039/C29690001296

DO - 10.1039/C29690001296

M3 - 文章

AN - SCOPUS:37049138427

SN - 0022-4936

SP - 1296

EP - 1297

JO - Journal of the Chemical Society, Chemical Transactions

JF - Journal of the Chemical Society, Chemical Transactions

IS - 22

ER -

A fast reversible equilibrium in the reaction of olefins with mercuric trifluoroacetate in aprotic solvents. Nature of the addition compounds

Abstract

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