Additive modification of the polymerization and properties of an acrylic bone cement

Jen Ming Yang; Jiing Shen Shyu; Hsin Lung Chen

doi:10.1002/pen.10216

Additive modification of the polymerization and properties of an acrylic bone cement

Jen Ming Yang^*, Jiing Shen Shyu, Hsin Lung Chen

^*Corresponding author for this work

Department of Chemical and Materials Engineering

Chang Gung University

Research output: Contribution to journal › Journal Article › peer-review

9 Scopus citations

Abstract

A commercial surgical bone cement has been modified by adding tricalcium phosphate (TCP), hydroxyethyl methacrylate (HEMA), and ethylene glycol dimethacrylate (EGDMA). The effects of the addition of TCP, HEMA, and EGDMA on the vinyl polymerization kinetics and thermal stability of the bone cement have been evaluated. The reaction rate constants (k) were determined from a kinetic analysis. The separate and combined effects of TCP, HEMA, and EGDMA contents on the rate and the heat of polymerization can be explained by the frequency factor and the activation energy. The decomposition temperature of the modified acrylic bone cement was studied by thermogravimetry. The decomposition temperature increased with TCP content, whereas HEMA and EGDMA had little effect on the decompositon temperature.

Original language	English
Pages (from-to)	530-533
Number of pages	4
Journal	Polymer Engineering and Science
Volume	38
Issue number	3
DOIs	https://doi.org/10.1002/pen.10216
State	Published - 1998

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title = "Additive modification of the polymerization and properties of an acrylic bone cement",

abstract = "A commercial surgical bone cement has been modified by adding tricalcium phosphate (TCP), hydroxyethyl methacrylate (HEMA), and ethylene glycol dimethacrylate (EGDMA). The effects of the addition of TCP, HEMA, and EGDMA on the vinyl polymerization kinetics and thermal stability of the bone cement have been evaluated. The reaction rate constants (k) were determined from a kinetic analysis. The separate and combined effects of TCP, HEMA, and EGDMA contents on the rate and the heat of polymerization can be explained by the frequency factor and the activation energy. The decomposition temperature of the modified acrylic bone cement was studied by thermogravimetry. The decomposition temperature increased with TCP content, whereas HEMA and EGDMA had little effect on the decompositon temperature.",

author = "Yang, {Jen Ming} and Shyu, {Jiing Shen} and Chen, {Hsin Lung}",

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T1 - Additive modification of the polymerization and properties of an acrylic bone cement

AU - Yang, Jen Ming

AU - Shyu, Jiing Shen

AU - Chen, Hsin Lung

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N2 - A commercial surgical bone cement has been modified by adding tricalcium phosphate (TCP), hydroxyethyl methacrylate (HEMA), and ethylene glycol dimethacrylate (EGDMA). The effects of the addition of TCP, HEMA, and EGDMA on the vinyl polymerization kinetics and thermal stability of the bone cement have been evaluated. The reaction rate constants (k) were determined from a kinetic analysis. The separate and combined effects of TCP, HEMA, and EGDMA contents on the rate and the heat of polymerization can be explained by the frequency factor and the activation energy. The decomposition temperature of the modified acrylic bone cement was studied by thermogravimetry. The decomposition temperature increased with TCP content, whereas HEMA and EGDMA had little effect on the decompositon temperature.

AB - A commercial surgical bone cement has been modified by adding tricalcium phosphate (TCP), hydroxyethyl methacrylate (HEMA), and ethylene glycol dimethacrylate (EGDMA). The effects of the addition of TCP, HEMA, and EGDMA on the vinyl polymerization kinetics and thermal stability of the bone cement have been evaluated. The reaction rate constants (k) were determined from a kinetic analysis. The separate and combined effects of TCP, HEMA, and EGDMA contents on the rate and the heat of polymerization can be explained by the frequency factor and the activation energy. The decomposition temperature of the modified acrylic bone cement was studied by thermogravimetry. The decomposition temperature increased with TCP content, whereas HEMA and EGDMA had little effect on the decompositon temperature.

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DO - 10.1002/pen.10216

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SP - 530

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JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

IS - 3

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Additive modification of the polymerization and properties of an acrylic bone cement

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