Adsorption of silver ions on polypyrrole embedded electrospun nanofibrous polyethersulfone membranes

Jiunn Jong Wu, Hsiu Wen Lee, Jiann Hwa You, Yi Chuan Kau, Shih Jung Liu*

*Corresponding author for this work

Research output: Contribution to journalJournal Article peer-review

27 Scopus citations

Abstract

In this study we developed polypyrrole embedded electrospun nanofibrous polyethersulfone nanofibrous membranes for the removal of silver ions. Polypyrrole and polyethersulfone dissolved in N-methyl-2-pyrrolidone (NMP) were electrospun into nanofibrous membranes via an electrospinning process. The morphology of as-spun polypyrrole/polyethersulfone nanofibers was examined by scanning electron microscopy. The average diameter of electrospun nanofibers ranged from 410. nm to 540. nm. The adsorption capability of nanofibrous polypyrrole/polyethersulfone membranes was measured and compared with that of bulk polypyrrole. The influence of various process conditions on adsorption efficiency was also examined. The experimental results suggested that the electrospun nanofibrous membranes exhibited good silver ion uptake capabilities. The metal uptake of nanofibrous membranes increased with the initial metal ion concentrations and the pH value, while decreased with the temperature and the filtering rate of the solutions. Furthermore, the electrospun membrane could be reused after the recovery process.

Original languageEnglish
Pages (from-to)145-151
Number of pages7
JournalJournal of Colloid and Interface Science
Volume420
DOIs
StatePublished - 15 04 2014

Keywords

  • Electrospinning
  • Nanofibrous membranes
  • Polyethersulfone
  • Polypyrrole
  • Silver ion removal

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