Average properties of polymer blends formed between two polydisperse reactive polymers

Lie Ding Shiau

doi:10.1016/S0032-3861(97)00424-2

Average properties of polymer blends formed between two polydisperse reactive polymers

Lie Ding Shiau^*

^*Corresponding author for this work

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Journal Article › peer-review

3 Scopus citations

Abstract

A general model for calculating the average properties of the copolymer formed between two polydisperse reactive polymers is developed. M_n, M_w, M_z, M_{z + 1} and other higher average molecular weights can all be described as a function of the reaction conversion and the average properties of two reactive polymers directly without calculation of the complete distribution. The predictive capacity of the model is limited to reaction before gelation and can be used for prediction of the gel point. The model is explicitly formulated and can therefore be readily applied.

Original language	English
Pages (from-to)	1317-1326
Number of pages	10
Journal	Polymer
Volume	39
Issue number	6-7
DOIs	https://doi.org/10.1016/S0032-3861(97)00424-2
State	Published - 03 1998

Keywords

Average properties
Copolymers
Mathematical modelling

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10.1016/S0032-3861(97)00424-2

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title = "Average properties of polymer blends formed between two polydisperse reactive polymers",

abstract = "A general model for calculating the average properties of the copolymer formed between two polydisperse reactive polymers is developed. Mn, Mw, Mz, Mz + 1 and other higher average molecular weights can all be described as a function of the reaction conversion and the average properties of two reactive polymers directly without calculation of the complete distribution. The predictive capacity of the model is limited to reaction before gelation and can be used for prediction of the gel point. The model is explicitly formulated and can therefore be readily applied.",

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author = "Shiau, {Lie Ding}",

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AB - A general model for calculating the average properties of the copolymer formed between two polydisperse reactive polymers is developed. Mn, Mw, Mz, Mz + 1 and other higher average molecular weights can all be described as a function of the reaction conversion and the average properties of two reactive polymers directly without calculation of the complete distribution. The predictive capacity of the model is limited to reaction before gelation and can be used for prediction of the gel point. The model is explicitly formulated and can therefore be readily applied.

KW - Average properties

KW - Copolymers

KW - Mathematical modelling

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M3 - 文章

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SN - 0032-3861

VL - 39

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JO - Polymer

JF - Polymer

IS - 6-7

ER -

Average properties of polymer blends formed between two polydisperse reactive polymers

Abstract

Keywords

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