TY - JOUR
T1 - Carrier optimization and reduced thermal conductivity leading to enhanced thermoelectric performance in (Mg, S) co-doped AgSbTe2
AU - Ganesan, Peramaiyan
AU - Gantepogu, Chandra Shekar
AU - Duraisamy, Sidharth
AU - Meledath Valiyaveettil, Suneesh
AU - Tsai, Wei Han
AU - Hsing, Cheng Rong
AU - Lin, Kung Hsuan
AU - Chen, Kuei Hsien
AU - Chen, Yang Yuan
AU - Wu, Maw Kuen
N1 - Publisher Copyright:
© 2024 Elsevier Ltd
PY - 2024/3
Y1 - 2024/3
N2 - Optimizing materials' electrical and thermal properties takes time and effort to achieve high thermoelectric performance. However, the appropriate dopants based on the solution can mitigate the difficulties and increase the overall thermoelectric performance. We have investigated the influence of (Mg, S) doping on the thermoelectric properties of AgSb1−xMgxTe2−ySy (x = 0.02, 0.03 and 0.04; y = 0.05, 0.1 and 0.15). AgSbTe2 likely possesses a cationic disorder due to its significant cationic radii mismatch and cationic charge imbalance between Ag1+ (115 p.m.) and Sb3+ (76 p.m.), leading to poor electronic transport properties. We demonstrate that decreasing the cationic charge imbalance (Mg2+ (72 p.m.), Zn2+ (74 p.m.) and Ca2+ (100 p.m.)) or ionic radii (Y3+ (96 p.m.)) can substantially decrease the cationic disorder in AgSbTe2. Magnesium doping considerably increased the hole carrier concentration from ∼4.38 × 1019 cm−3 to ∼9.17 × 1019 cm−3. It increased the band gap from 0.35 eV to 0.39 eV, which boosts the density of states effective mass (md*) and suppresses the bipolar contribution. Co-doping (Mg, S) in AgSbTe2 enhances the power factor from ∼8.58 to ∼17.18 μW cm−1 K−2 at 600 K, resulting from the enhanced carrier concentration, weighted mobility and quality factor, and valence band convergence. The sulfur substitution at the tellurium site significantly suppresses the bipolar contribution by increasing the bandgap/reducing minority charge carriers, which is better than Se-doping. We predicted a high thermoelectric conversion efficiency of ≈13.6% for the temperature gradient of 300 K, which shows excellent potential for mid-temperature thermoelectric device applications. Our co-doping strategy using eco-friendly and earth-abundant elements synergistically optimizes the power factor and thermal conductivity of AgSbTe2, leading to an improved figure of merit of about ∼1.96 at 600 K.
AB - Optimizing materials' electrical and thermal properties takes time and effort to achieve high thermoelectric performance. However, the appropriate dopants based on the solution can mitigate the difficulties and increase the overall thermoelectric performance. We have investigated the influence of (Mg, S) doping on the thermoelectric properties of AgSb1−xMgxTe2−ySy (x = 0.02, 0.03 and 0.04; y = 0.05, 0.1 and 0.15). AgSbTe2 likely possesses a cationic disorder due to its significant cationic radii mismatch and cationic charge imbalance between Ag1+ (115 p.m.) and Sb3+ (76 p.m.), leading to poor electronic transport properties. We demonstrate that decreasing the cationic charge imbalance (Mg2+ (72 p.m.), Zn2+ (74 p.m.) and Ca2+ (100 p.m.)) or ionic radii (Y3+ (96 p.m.)) can substantially decrease the cationic disorder in AgSbTe2. Magnesium doping considerably increased the hole carrier concentration from ∼4.38 × 1019 cm−3 to ∼9.17 × 1019 cm−3. It increased the band gap from 0.35 eV to 0.39 eV, which boosts the density of states effective mass (md*) and suppresses the bipolar contribution. Co-doping (Mg, S) in AgSbTe2 enhances the power factor from ∼8.58 to ∼17.18 μW cm−1 K−2 at 600 K, resulting from the enhanced carrier concentration, weighted mobility and quality factor, and valence band convergence. The sulfur substitution at the tellurium site significantly suppresses the bipolar contribution by increasing the bandgap/reducing minority charge carriers, which is better than Se-doping. We predicted a high thermoelectric conversion efficiency of ≈13.6% for the temperature gradient of 300 K, which shows excellent potential for mid-temperature thermoelectric device applications. Our co-doping strategy using eco-friendly and earth-abundant elements synergistically optimizes the power factor and thermal conductivity of AgSbTe2, leading to an improved figure of merit of about ∼1.96 at 600 K.
KW - Atomic ordering
KW - Metal-insulator transition
KW - Pseudo binary compound
KW - Solid solution point defect
KW - Thermoelectric material
UR - http://www.scopus.com/inward/record.url?scp=85184994184&partnerID=8YFLogxK
U2 - 10.1016/j.mtphys.2024.101358
DO - 10.1016/j.mtphys.2024.101358
M3 - 文章
AN - SCOPUS:85184994184
SN - 2542-5293
VL - 42
JO - Materials Today Physics
JF - Materials Today Physics
M1 - 101358
ER -