Coalescence of crystalline microdomains driven by postannealing in a block copolymer blend

Yen Yu Huang; Hsin Lung Chen; Hsiu Chun Li; Tsang Lang Lin; J. S. Lin

doi:10.1021/ma0213201

Coalescence of crystalline microdomains driven by postannealing in a block copolymer blend

Yen Yu Huang, Hsin Lung Chen^*, Hsiu Chun Li, Tsang Lang Lin, J. S. Lin

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

19 Scopus citations

Abstract

The coalescence of crystalline microdomains driven by annealing a PEO-b-PB/PB blend at temperatures near the onsets of melting of the as-crystallized samples was reported. Two or three crystalline domains were found to merge into highly elongated prolate or a rodlike domain through the postannealing. Since nearly all microdomains remained semicrystalline during the treatment, this coalescence process was distinguished from that found in the crystallization process or that associated with the order-order transition from spherical-to-cylindrical domains in block copolymer melt.

Original language	English
Pages (from-to)	282-285
Number of pages	4
Journal	Macromolecules
Volume	36
Issue number	2
DOIs	https://doi.org/10.1021/ma0213201
State	Published - 28 01 2003
Externally published	Yes

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abstract = "The coalescence of crystalline microdomains driven by annealing a PEO-b-PB/PB blend at temperatures near the onsets of melting of the as-crystallized samples was reported. Two or three crystalline domains were found to merge into highly elongated prolate or a rodlike domain through the postannealing. Since nearly all microdomains remained semicrystalline during the treatment, this coalescence process was distinguished from that found in the crystallization process or that associated with the order-order transition from spherical-to-cylindrical domains in block copolymer melt.",

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AU - Huang, Yen Yu

AU - Chen, Hsin Lung

AU - Li, Hsiu Chun

AU - Lin, Tsang Lang

AU - Lin, J. S.

PY - 2003/1/28

Y1 - 2003/1/28

N2 - The coalescence of crystalline microdomains driven by annealing a PEO-b-PB/PB blend at temperatures near the onsets of melting of the as-crystallized samples was reported. Two or three crystalline domains were found to merge into highly elongated prolate or a rodlike domain through the postannealing. Since nearly all microdomains remained semicrystalline during the treatment, this coalescence process was distinguished from that found in the crystallization process or that associated with the order-order transition from spherical-to-cylindrical domains in block copolymer melt.

AB - The coalescence of crystalline microdomains driven by annealing a PEO-b-PB/PB blend at temperatures near the onsets of melting of the as-crystallized samples was reported. Two or three crystalline domains were found to merge into highly elongated prolate or a rodlike domain through the postannealing. Since nearly all microdomains remained semicrystalline during the treatment, this coalescence process was distinguished from that found in the crystallization process or that associated with the order-order transition from spherical-to-cylindrical domains in block copolymer melt.

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VL - 36

SP - 282

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JO - Macromolecules

JF - Macromolecules

IS - 2

ER -

Coalescence of crystalline microdomains driven by postannealing in a block copolymer blend

Abstract

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