Comparative Equilibrium Studies on the Sorption off Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger

Ruey Shin Juang; Muh Lian Chen

doi:10.1080/01496399708000943

Comparative Equilibrium Studies on the Sorption off Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger

Ruey Shin Juang^*
, Muh Lian Chen

^*Corresponding author for this work

Yuan Ze University

Research output: Contribution to journal › Journal Article › peer-review

21 Scopus citations

Abstract

The distribution of five metal ions (M^m+) including Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) between dilute sulfate solutions and macrporous resins containing di(2-ethylhexyl)phosphoric acid (D2EHPA, HR) was investigated. Experiments were carried out as a function of aqueous pH, D2EHPA concentration in the resin phase, and temperature. The equilibrium data were numerically analyzed. It was shown that the sorption reaction could be described by assuming the formation of metal complexes with a general composition MR_m(HR_n) in the resin phase. For several systems a change of complex stoichiometry with temperature was observed and discussed. The apparent thermodynamic data for the formation of these complexes were also calculated.

Original language	English
Pages (from-to)	1017-1035
Number of pages	19
Journal	Separation Science and Technology
Volume	32
Issue number	5
DOIs	https://doi.org/10.1080/01496399708000943
State	Published - 1997
Externally published	Yes

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title = "Comparative Equilibrium Studies on the Sorption off Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger",

abstract = "The distribution of five metal ions (Mm+) including Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) between dilute sulfate solutions and macrporous resins containing di(2-ethylhexyl)phosphoric acid (D2EHPA, HR) was investigated. Experiments were carried out as a function of aqueous pH, D2EHPA concentration in the resin phase, and temperature. The equilibrium data were numerically analyzed. It was shown that the sorption reaction could be described by assuming the formation of metal complexes with a general composition MRm(HRn) in the resin phase. For several systems a change of complex stoichiometry with temperature was observed and discussed. The apparent thermodynamic data for the formation of these complexes were also calculated.",

author = "Juang, \{Ruey Shin\} and Chen, \{Muh Lian\}",

year = "1997",

doi = "10.1080/01496399708000943",

language = "英语",

volume = "32",

pages = "1017--1035",

journal = "Separation Science and Technology",

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T1 - Comparative Equilibrium Studies on the Sorption off Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger

AU - Juang, Ruey Shin

AU - Chen, Muh Lian

PY - 1997

Y1 - 1997

N2 - The distribution of five metal ions (Mm+) including Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) between dilute sulfate solutions and macrporous resins containing di(2-ethylhexyl)phosphoric acid (D2EHPA, HR) was investigated. Experiments were carried out as a function of aqueous pH, D2EHPA concentration in the resin phase, and temperature. The equilibrium data were numerically analyzed. It was shown that the sorption reaction could be described by assuming the formation of metal complexes with a general composition MRm(HRn) in the resin phase. For several systems a change of complex stoichiometry with temperature was observed and discussed. The apparent thermodynamic data for the formation of these complexes were also calculated.

AB - The distribution of five metal ions (Mm+) including Fe(III), Co(II), Ni(II), Cu(II), and Zn(II) between dilute sulfate solutions and macrporous resins containing di(2-ethylhexyl)phosphoric acid (D2EHPA, HR) was investigated. Experiments were carried out as a function of aqueous pH, D2EHPA concentration in the resin phase, and temperature. The equilibrium data were numerically analyzed. It was shown that the sorption reaction could be described by assuming the formation of metal complexes with a general composition MRm(HRn) in the resin phase. For several systems a change of complex stoichiometry with temperature was observed and discussed. The apparent thermodynamic data for the formation of these complexes were also calculated.

UR - https://www.scopus.com/pages/publications/0000647563

U2 - 10.1080/01496399708000943

DO - 10.1080/01496399708000943

M3 - 文章

AN - SCOPUS:0000647563

SN - 0149-6395

VL - 32

SP - 1017

EP - 1035

JO - Separation Science and Technology

JF - Separation Science and Technology

IS - 5

ER -

Comparative Equilibrium Studies on the Sorption off Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger

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