Comparative study of crystallization and lamellae orientation of isotactic polypropylene by rapid heat cycle molding and conventional injection molding

The crystallization and orientation of isotactic polypropylene (iPP) molded by rapid heat cycle molding (RHCM) and conventional injection molding (CIM) were studied. Due to the varying cooling rates and shearing, the molded parts exhibited a multilayered structure (skin, shear and core) across the part thickness, reflecting different degrees of crystallization and lamellae orientation of iPP. The morphology evolution of RHCM products was discussed based on the comparative research of morphology and structure at multiple sites on the RHCM and CIM specimens. Scanning electron microscopy (SEM) and wide angle X-ray diffraction (WAXD) were used to analyze the thickness, crystallinity and lamellae orientation of these three distinct layers. The crystallization and lamellae orientation of iPP correlated strongly with the multilayered structure. In the RHCM process, one side of the mold is equipped with the rapid heat cycle function. The thickness and lamellae orientation next to the heated surface were less than that of the opposite skin layer without heating. Meanwhile, the crystallinity was greater than that of the opposite skin layer.