Copper-mediated trimethylsilyl azide in amination of bromoflavonoids to synthesize unique aminoflavonoids

Tzenge Lien Shih; Chi En Chou; Wen Yu Liao; Chih Ang Hsiao

doi:10.1016/j.tet.2014.04.022

Copper-mediated trimethylsilyl azide in amination of bromoflavonoids to synthesize unique aminoflavonoids

Tzenge Lien Shih^*
, Chi En Chou
, Wen Yu Liao
, Chih Ang Hsiao

^*Corresponding author for this work

Tamkang University

Research output: Contribution to journal › Journal Article › peer-review

11 Scopus citations

Abstract

Aminoflavonoids are unique antioxidants comparing to other abundant flavonoids in nature. Their syntheses and biological activities were scarcely reported. An effectively copper-mediated amination of the corresponding bromoflavonoids to synthesize a series of new aminoflavonoids is described.

Original language	English
Pages (from-to)	3657-3664
Number of pages	8
Journal	Tetrahedron
Volume	70
Issue number	23
DOIs	https://doi.org/10.1016/j.tet.2014.04.022
State	Published - 10 06 2014
Externally published	Yes

Keywords

Aminoflavonoids
Baker-Venkataraman rearrangement
Claisen-Schmidt reaction
Copper-mediated amination
Trimethylsilyl azide

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10.1016/j.tet.2014.04.022

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title = "Copper-mediated trimethylsilyl azide in amination of bromoflavonoids to synthesize unique aminoflavonoids",

abstract = "Aminoflavonoids are unique antioxidants comparing to other abundant flavonoids in nature. Their syntheses and biological activities were scarcely reported. An effectively copper-mediated amination of the corresponding bromoflavonoids to synthesize a series of new aminoflavonoids is described.",

keywords = "Aminoflavonoids, Baker-Venkataraman rearrangement, Claisen-Schmidt reaction, Copper-mediated amination, Trimethylsilyl azide",

author = "Shih, \{Tzenge Lien\} and Chou, \{Chi En\} and Liao, \{Wen Yu\} and Hsiao, \{Chih Ang\}",

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T1 - Copper-mediated trimethylsilyl azide in amination of bromoflavonoids to synthesize unique aminoflavonoids

AU - Shih, Tzenge Lien

AU - Chou, Chi En

AU - Liao, Wen Yu

AU - Hsiao, Chih Ang

PY - 2014/6/10

Y1 - 2014/6/10

N2 - Aminoflavonoids are unique antioxidants comparing to other abundant flavonoids in nature. Their syntheses and biological activities were scarcely reported. An effectively copper-mediated amination of the corresponding bromoflavonoids to synthesize a series of new aminoflavonoids is described.

AB - Aminoflavonoids are unique antioxidants comparing to other abundant flavonoids in nature. Their syntheses and biological activities were scarcely reported. An effectively copper-mediated amination of the corresponding bromoflavonoids to synthesize a series of new aminoflavonoids is described.

KW - Aminoflavonoids

KW - Baker-Venkataraman rearrangement

KW - Claisen-Schmidt reaction

KW - Copper-mediated amination

KW - Trimethylsilyl azide

UR - https://www.scopus.com/pages/publications/84899929369

U2 - 10.1016/j.tet.2014.04.022

DO - 10.1016/j.tet.2014.04.022

M3 - 文章

AN - SCOPUS:84899929369

SN - 0040-4020

VL - 70

SP - 3657

EP - 3664

JO - Tetrahedron

JF - Tetrahedron

IS - 23

ER -

Copper-mediated trimethylsilyl azide in amination of bromoflavonoids to synthesize unique aminoflavonoids

Abstract

Keywords

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