Crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase

Hsin Lung Chen; Hsiu Chun Li; Yen Yu Huang; Fang Chyou Chiu

doi:10.1021/ma011748k

Crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase

Hsin Lung Chen^*, Hsiu Chun Li, Yen Yu Huang, Fang Chyou Chiu

^*Corresponding author for this work

Department of Chemical and Materials Engineering

National Tsing Hua University

Research output: Contribution to journal › Journal Article › peer-review

40 Scopus citations

Abstract

The crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase was presented. The crystallization of polyethylene oxide (PEO) blocks within the spherical microdomains were induced at the temperatures above T_g of polybutadiene (PB) and the domains were dispersed in a soft matrix during crystallization. Results showed that the spherical microdomains present in the melt state of a PEO-b-PB/PB blend system were not preserved upon crystallization.

Original language	English
Pages (from-to)	2417-2422
Number of pages	6
Journal	Macromolecules
Volume	35
Issue number	6
DOIs	https://doi.org/10.1021/ma011748k
State	Published - 12 03 2002

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10.1021/ma011748k

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title = "Crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase",

abstract = "The crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase was presented. The crystallization of polyethylene oxide (PEO) blocks within the spherical microdomains were induced at the temperatures above Tg of polybutadiene (PB) and the domains were dispersed in a soft matrix during crystallization. Results showed that the spherical microdomains present in the melt state of a PEO-b-PB/PB blend system were not preserved upon crystallization.",

author = "Chen, {Hsin Lung} and Li, {Hsiu Chun} and Huang, {Yen Yu} and Chiu, {Fang Chyou}",

year = "2002",

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T1 - Crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase

AU - Chen, Hsin Lung

AU - Li, Hsiu Chun

AU - Huang, Yen Yu

AU - Chiu, Fang Chyou

PY - 2002/3/12

Y1 - 2002/3/12

N2 - The crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase was presented. The crystallization of polyethylene oxide (PEO) blocks within the spherical microdomains were induced at the temperatures above Tg of polybutadiene (PB) and the domains were dispersed in a soft matrix during crystallization. Results showed that the spherical microdomains present in the melt state of a PEO-b-PB/PB blend system were not preserved upon crystallization.

AB - The crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase was presented. The crystallization of polyethylene oxide (PEO) blocks within the spherical microdomains were induced at the temperatures above Tg of polybutadiene (PB) and the domains were dispersed in a soft matrix during crystallization. Results showed that the spherical microdomains present in the melt state of a PEO-b-PB/PB blend system were not preserved upon crystallization.

UR - http://www.scopus.com/inward/record.url?scp=0037066232&partnerID=8YFLogxK

U2 - 10.1021/ma011748k

DO - 10.1021/ma011748k

M3 - 文章

AN - SCOPUS:0037066232

SN - 0024-9297

VL - 35

SP - 2417

EP - 2422

JO - Macromolecules

JF - Macromolecules

IS - 6

ER -

Crystallization-induced deformation of spherical microdomains in block copolymer blends consisting of a soft amorphous phase

Abstract

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