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Defect structure of non-stoichiometric Cu-I-III-VI2 chalcopyrite semiconductors

  • H. Y. Ueng*
  • , H. L. Hwang
  • *Corresponding author for this work
  • National Sun Yat-sen University
  • National Tsing Hua University

Research output: Contribution to journalJournal Article peer-review

18 Scopus citations

Abstract

The defect structure of CuMX2 (M≡In, Ga and X≡S, Se, Te) was investigated. The defect concentrations were derived as a function of stoichiometric composition, and the carrier concentrations were calculated quantitatively using a theoretical defect model, which could be used to select the proper region of stoichiometry for device designs with specified carrier concentrations. The compensation reaction between dopants and intrinsic defects in CuMX2 compound semiconductors is quantitatively illustrated.

Original languageEnglish
Pages (from-to)261-267
Number of pages7
JournalMaterials Science and Engineering: B
Volume12
Issue number3
DOIs
StatePublished - 01 02 1992
Externally publishedYes

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