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Enhancement of charge collection at shorter wavelengths from alternative CdS deposition conditions for high efficiency CZTSSe solar cells

  • Venkatesh Tunuguntla
  • , Wei Chao Chen
  • , Tyler D. Newman
  • , Cheng Ying Chen
  • , Meng Chia Hsieh
  • , Shao Hung Lu
  • , Chaochin Su
  • , Li Chyong Chen*
  • , Kuei Hsien Chen
  • *Corresponding author for this work
  • Academia Sinica Taiwan HQ
  • National Tsing Hua University
  • National Taiwan University
  • University of California at Berkeley
  • National Taipei University of Technology

Research output: Contribution to journal › Journal Article › peer-review

15 Scopus citations

Abstract

A cadmium sulfide (CdS) layer with a thickness of 37±5 nm is deposited onto a Cu2ZnSn(SSe)4 absorber layer using Cd(NO3)2 precursor at pH 11.8 via chemical bath deposition. Full devices fabricated with the thin CdS layer show improved champion efficiency of 6.97%, compared with the 5.91% efficiency of the control device, which can be attributed to the increased current density from reduced light reflection in the visible region and enhanced charge collection in the shorter wavelength region.

Original languageEnglish
Pages (from-to)49-54
Number of pages6
JournalSolar Energy Materials and Solar Cells
Volume149
DOIs
StatePublished - 05 2016
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Cd(NO)
  • CdS thickness
  • CZTSSe solar cells
  • Increase in current density
  • Increase in EQE

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