Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid

Tzenge Lien Shih; Ya Ling Lin

doi:10.1081/SCC-200063960

Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid

Tzenge Lien Shih^*, Ya Ling Lin

^*Corresponding author for this work

Tamkang University

Research output: Contribution to journal › Journal Article › peer-review

8 Scopus citations

Abstract

Highly stereoselective epoxidations have been achieved in both cyclohexylidene acetal and butane 2,3-bisacetal (BBA) protection of (1,4,5)-cyclohex-2-ene-triols. These epoxy derivatives are all derived from D-(-)-quinic acid and can be used for the synthesis of muco-, (+)-epi-, (+)-vibo, (-)-talo, and (-)-galaquercitols.

Original language	English
Pages (from-to)	1809-1817
Number of pages	9
Journal	Synthetic Communications
Volume	35
Issue number	13
DOIs	https://doi.org/10.1081/SCC-200063960
State	Published - 2005
Externally published	Yes

Keywords

D-(-)-Quinic acid
Epoxidation
Quercitol

Access to Document

10.1081/SCC-200063960

Cite this

@article{ae0e2a2fc1f049ed80a111d625e24167,

title = "Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid",

abstract = "Highly stereoselective epoxidations have been achieved in both cyclohexylidene acetal and butane 2,3-bisacetal (BBA) protection of (1,4,5)-cyclohex-2-ene-triols. These epoxy derivatives are all derived from D-(-)-quinic acid and can be used for the synthesis of muco-, (+)-epi-, (+)-vibo, (-)-talo, and (-)-galaquercitols.",

keywords = "D-(-)-Quinic acid, Epoxidation, Quercitol",

author = "Shih, {Tzenge Lien} and Lin, {Ya Ling}",

year = "2005",

doi = "10.1081/SCC-200063960",

language = "英语",

volume = "35",

pages = "1809--1817",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis Ltd.",

number = "13",

}

TY - JOUR

T1 - Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid

AU - Shih, Tzenge Lien

AU - Lin, Ya Ling

PY - 2005

Y1 - 2005

N2 - Highly stereoselective epoxidations have been achieved in both cyclohexylidene acetal and butane 2,3-bisacetal (BBA) protection of (1,4,5)-cyclohex-2-ene-triols. These epoxy derivatives are all derived from D-(-)-quinic acid and can be used for the synthesis of muco-, (+)-epi-, (+)-vibo, (-)-talo, and (-)-galaquercitols.

AB - Highly stereoselective epoxidations have been achieved in both cyclohexylidene acetal and butane 2,3-bisacetal (BBA) protection of (1,4,5)-cyclohex-2-ene-triols. These epoxy derivatives are all derived from D-(-)-quinic acid and can be used for the synthesis of muco-, (+)-epi-, (+)-vibo, (-)-talo, and (-)-galaquercitols.

KW - D-(-)-Quinic acid

KW - Epoxidation

KW - Quercitol

UR - http://www.scopus.com/inward/record.url?scp=22044433956&partnerID=8YFLogxK

U2 - 10.1081/SCC-200063960

DO - 10.1081/SCC-200063960

M3 - 文章

AN - SCOPUS:22044433956

SN - 0039-7911

VL - 35

SP - 1809

EP - 1817

JO - Synthetic Communications

JF - Synthetic Communications

IS - 13

ER -

Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this