Fabrication of a Potential Electrodeposited Nanocomposite for Dental Applications

In the present study, a nanocrystalline Ni-Fe matrix with reinforced TiO₂ nanoparticles as a functional nanocomposite material was fabricated by pulsed current electroforming in UV-LIGA (lithography, electroplating, and molding). The influences of TiO₂ nanoparticles on the Ni-Fe nanocomposite deposition were also investigated using scanning electron microscopy, transmission electron microscopy, and in vitro cytotoxicity assay. It was found that the Ni-Fe nanocomposite with 5 wt.% TiO₂ nanoparticles showed a smooth surface and better dispersion property. When the Ni-Fe nanocomposite is combined with 20 wt.% TiO₂, it resulted in congeries of TiO₂ nanoparticles. In addition, TiO₂ nanoparticles possessed better dispersion properties as performed in pulse current electrodeposition. The microstructure of the electrodeposited Ni-Fe-TiO₂ nanocomposite was a FeNi3 phase containing anatase nano-TiO₂. Moreover, the electrodeposited Ni-Fe-5 wt.% TiO₂ nanocomposite exhibited a smooth surface and structural integrity. Cytotoxicity assay results also proved that the Ni-Fe nanocomposite with different concentrations of TiO₂ nanoparticles had good biocompatibility. Therefore, the optimization of pulse current electroforming parameters was successfully applied to fabricate the Ni-Fe-TiO₂ nanocomposite, and thus could be used as an endodontic file material for dental applications.