TY - JOUR
T1 - Fabrication of gadolinium zinc oxide anchored with functionalized-SWCNT planted on glassy carbon electrode
T2 - Potential detection of psychotropic drug (phenothiazine) in biotic sample
AU - Pulikkutty, Subramaniyan
AU - Manjula, Natesan
AU - Chen, Tse Wei
AU - Chen, Shen Ming
AU - Lou, Bih Show
AU - Siddiqui, Masoom Raza
AU - Wabaidur, Saikh Mohammad
AU - Ali, Mohammad Ajmal
N1 - Publisher Copyright:
© 2022 Elsevier B.V.
PY - 2022/8/1
Y1 - 2022/8/1
N2 - Fabricating the designing and developing of an easy, sophisticated synthetic framework with a highly effective and dual-purpose catalyst with affordable cost for clean energy harvesters has been a long-standing challenging task. Herein, we explored a clear and simple design for fabricating gadolinium zinc oxide hybrid nanostructure combined with functionalized single-walled carbon nanotube (GZO/f–SWCNT) as a well-organized concrete conductor material for the electrochemical sensor of phenothiazine (PHZ). The pure GZO electrocatalysts were made by the cost-effective co-precipitation technique. Numerous analytical methods were employed to examine the physio-chemical properties of the synthesized nanomaterials. These results explicitly show and validate the development of a composite substance. The electrochemical potential efficacy of the constructed electrode (GZO/f–SWCNT/GCE) was confirmed through apply the PHZ determination with the dynamic linear range of 0.01 µM–98.51 µM, the sensitivity and detection limit were calculated to be 2.981 μA μM−1 cm−2 and 0.005 µM. When compared to individual material, the composite material GZO/f–SWCNT showed considerably higher electrocatalytic behavior towards the PHZ. Furthermore, the standard addition method performed PHZ determination in urine samples. Three parallel assessments yielded acceptable findings, with a relative standard deviation of 1.95–4.02% and 99–100.4% recovery. As a result, GZO/f–SWCNT proved to be a new potential material for the PHZ sensor.
AB - Fabricating the designing and developing of an easy, sophisticated synthetic framework with a highly effective and dual-purpose catalyst with affordable cost for clean energy harvesters has been a long-standing challenging task. Herein, we explored a clear and simple design for fabricating gadolinium zinc oxide hybrid nanostructure combined with functionalized single-walled carbon nanotube (GZO/f–SWCNT) as a well-organized concrete conductor material for the electrochemical sensor of phenothiazine (PHZ). The pure GZO electrocatalysts were made by the cost-effective co-precipitation technique. Numerous analytical methods were employed to examine the physio-chemical properties of the synthesized nanomaterials. These results explicitly show and validate the development of a composite substance. The electrochemical potential efficacy of the constructed electrode (GZO/f–SWCNT/GCE) was confirmed through apply the PHZ determination with the dynamic linear range of 0.01 µM–98.51 µM, the sensitivity and detection limit were calculated to be 2.981 μA μM−1 cm−2 and 0.005 µM. When compared to individual material, the composite material GZO/f–SWCNT showed considerably higher electrocatalytic behavior towards the PHZ. Furthermore, the standard addition method performed PHZ determination in urine samples. Three parallel assessments yielded acceptable findings, with a relative standard deviation of 1.95–4.02% and 99–100.4% recovery. As a result, GZO/f–SWCNT proved to be a new potential material for the PHZ sensor.
KW - Biotic sample
KW - Coprecipitation
KW - Functionalized carbon nanotubes
KW - Gadolinium zinc oxide
KW - Phenothiazine
UR - http://www.scopus.com/inward/record.url?scp=85131967948&partnerID=8YFLogxK
U2 - 10.1016/j.jelechem.2022.116521
DO - 10.1016/j.jelechem.2022.116521
M3 - 文章
AN - SCOPUS:85131967948
SN - 1572-6657
VL - 918
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
M1 - 116521
ER -