Hardness variation and corrosion behavior of as-plated and annealed Cr-Ni alloy deposits electroplated in a trivalent chromium-based bath

Ching An Huang*, Che Kuan Lin, Chao Yu Chen

*Corresponding author for this work

Research output: Contribution to journalJournal Article peer-review

44 Scopus citations

Abstract

Cr-Ni alloy deposits with various concentrations of Cr, Ni were obtained with different electroplating current densities in a plating bath containing trivalent chromium and divalent nickel ions. The Cr-rich alloy deposit with a very high hardness of 1150 Hv can be obtained by annealing at 700 °C for 30 min. These alloys displayed poor corrosion resistance due to through-deposit cracking during annealing. For optimal hardness and corrosion resistance, we recommend a sequential two-step electrodeposition with Ni-rich alloy electroplating followed by Cr-rich alloy electroplating, or Cr/Ni alloy electrodeposition, to create a protective coating.

Original languageEnglish
Pages (from-to)3686-3691
Number of pages6
JournalSurface and Coatings Technology
Volume203
Issue number24
DOIs
StatePublished - 15 09 2009

Keywords

  • Corrosion
  • Cr-Ni alloy deposit
  • Hardness
  • Through-deposit cracking
  • Trivalent chromium

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