Highly efficient P3HT: C60 solar cell free of annealing process

Shu Hua Chan; Chia Sheng Lai; Hsin Lung Chen; Ching Ting; Chih Ping Chen

doi:10.1021/ma201425d

Highly efficient P3HT: C60 solar cell free of annealing process

Shu Hua Chan^*, Chia Sheng Lai, Hsin Lung Chen, Ching Ting, Chih Ping Chen

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

56 Scopus citations

Abstract

All conjugated C₆₀-containing block copolymers (BCPs) based on quasi-living Grignard metathesis (GRIM) polymerization have been designed and synthesized for application in polymer solar cells (PSCs). The C ₆₀-containing BCP can induce the formation of a self-organization nanostructure of P3HT domain. Moreover, this C₆₀-containing BCP serves as a compatibilizer to reduce the interfacial tension between the P3HT and C₆₀, thus help establishing a moderate phase-separated morphology with crystalline P3HT and C₆₀ domain. The performance up to 2.56%(AM 1.5G irradiation (100 mW/cm²)) of a P3HT:C60 device can be achieved by using C₆₀-BCP as additive without any post-treatment.

Original language	English
Pages (from-to)	8886-8891
Number of pages	6
Journal	Macromolecules
Volume	44
Issue number	22
DOIs	https://doi.org/10.1021/ma201425d
State	Published - 22 11 2011
Externally published	Yes

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@article{034f7b45a78747a9af42fab40803ac27,

title = "Highly efficient P3HT: C60 solar cell free of annealing process",

abstract = "All conjugated C60-containing block copolymers (BCPs) based on quasi-living Grignard metathesis (GRIM) polymerization have been designed and synthesized for application in polymer solar cells (PSCs). The C 60-containing BCP can induce the formation of a self-organization nanostructure of P3HT domain. Moreover, this C60-containing BCP serves as a compatibilizer to reduce the interfacial tension between the P3HT and C60, thus help establishing a moderate phase-separated morphology with crystalline P3HT and C60 domain. The performance up to 2.56\%(AM 1.5G irradiation (100 mW/cm2)) of a P3HT:C60 device can be achieved by using C60-BCP as additive without any post-treatment.",

author = "Chan, \{Shu Hua\} and Lai, \{Chia Sheng\} and Chen, \{Hsin Lung\} and Ching Ting and Chen, \{Chih Ping\}",

year = "2011",

month = nov,

day = "22",

doi = "10.1021/ma201425d",

language = "英语",

volume = "44",

pages = "8886--8891",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Highly efficient P3HT

T2 - C60 solar cell free of annealing process

AU - Chan, Shu Hua

AU - Lai, Chia Sheng

AU - Chen, Hsin Lung

AU - Ting, Ching

AU - Chen, Chih Ping

PY - 2011/11/22

Y1 - 2011/11/22

N2 - All conjugated C60-containing block copolymers (BCPs) based on quasi-living Grignard metathesis (GRIM) polymerization have been designed and synthesized for application in polymer solar cells (PSCs). The C 60-containing BCP can induce the formation of a self-organization nanostructure of P3HT domain. Moreover, this C60-containing BCP serves as a compatibilizer to reduce the interfacial tension between the P3HT and C60, thus help establishing a moderate phase-separated morphology with crystalline P3HT and C60 domain. The performance up to 2.56%(AM 1.5G irradiation (100 mW/cm2)) of a P3HT:C60 device can be achieved by using C60-BCP as additive without any post-treatment.

AB - All conjugated C60-containing block copolymers (BCPs) based on quasi-living Grignard metathesis (GRIM) polymerization have been designed and synthesized for application in polymer solar cells (PSCs). The C 60-containing BCP can induce the formation of a self-organization nanostructure of P3HT domain. Moreover, this C60-containing BCP serves as a compatibilizer to reduce the interfacial tension between the P3HT and C60, thus help establishing a moderate phase-separated morphology with crystalline P3HT and C60 domain. The performance up to 2.56%(AM 1.5G irradiation (100 mW/cm2)) of a P3HT:C60 device can be achieved by using C60-BCP as additive without any post-treatment.

UR - https://www.scopus.com/pages/publications/81255152593

U2 - 10.1021/ma201425d

DO - 10.1021/ma201425d

M3 - 文章

AN - SCOPUS:81255152593

SN - 0024-9297

VL - 44

SP - 8886

EP - 8891

JO - Macromolecules

JF - Macromolecules

IS - 22

ER -

Highly efficient P3HT: C60 solar cell free of annealing process

Abstract

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