Infrared study of benzene hydrogenation on Pt/SiO2 catalyst by co-adsorption of CO and benzene

Ching Shiun Chen; Jarrn Horng Lin; Hsiu Wei Chen; Chien Yuan Wang

doi:10.1007/s10562-005-8684-7

Infrared study of benzene hydrogenation on Pt/SiO₂ catalyst by co-adsorption of CO and benzene

Ching Shiun Chen^*, Jarrn Horng Lin, Hsiu Wei Chen, Chien Yuan Wang

^*Corresponding author for this work

Division of Natural Science

Research output: Contribution to journal › Journal Article › peer-review

11 Scopus citations

Abstract

FT-IR spectra of the co-adsorption of benzene and CO have been performed to identify the preferred adsorption sites of hydrogen and benzene on a Pt/SiO₂ catalyst for hydrogenation of benzene. Results of CO adsorbed on atop sites on Pt/SiO₂ includes: an α peak at 2091 cm ^-1, a β peak at 2080 cm^-1 and a γ peak at 2067 cm^-1 indicating three kinds of adsorption sites for dissociative hydrogen on Pt/SiO₂. The site of lowest CO stretching frequency offers stronger adsorbates-metal interaction for benzene and hydrogen. Hydrogen binding on the site of lowest CO stretching frequency before benzene adsorption significantly enhances the reaction rate of benzene hydrogenation.

Original language	English
Pages (from-to)	149-155
Number of pages	7
Journal	Catalysis Letters
Volume	105
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-005-8684-7
State	Published - 12 2005

Keywords

Benzene hydrogenation
CO adsorption
FTIR
Pt/SiO

Access to Document

10.1007/s10562-005-8684-7

Cite this

@article{ddd7325017a04bd7b225567e972cd758,

title = "Infrared study of benzene hydrogenation on Pt/SiO2 catalyst by co-adsorption of CO and benzene",

abstract = "FT-IR spectra of the co-adsorption of benzene and CO have been performed to identify the preferred adsorption sites of hydrogen and benzene on a Pt/SiO2 catalyst for hydrogenation of benzene. Results of CO adsorbed on atop sites on Pt/SiO2 includes: an α peak at 2091 cm -1, a β peak at 2080 cm-1 and a γ peak at 2067 cm-1 indicating three kinds of adsorption sites for dissociative hydrogen on Pt/SiO2. The site of lowest CO stretching frequency offers stronger adsorbates-metal interaction for benzene and hydrogen. Hydrogen binding on the site of lowest CO stretching frequency before benzene adsorption significantly enhances the reaction rate of benzene hydrogenation.",

keywords = "Benzene hydrogenation, CO adsorption, FTIR, Pt/SiO",

author = "Chen, {Ching Shiun} and Lin, {Jarrn Horng} and Chen, {Hsiu Wei} and Wang, {Chien Yuan}",

year = "2005",

month = dec,

doi = "10.1007/s10562-005-8684-7",

language = "英语",

volume = "105",

pages = "149--155",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "3-4",

}

TY - JOUR

T1 - Infrared study of benzene hydrogenation on Pt/SiO2 catalyst by co-adsorption of CO and benzene

AU - Chen, Ching Shiun

AU - Lin, Jarrn Horng

AU - Chen, Hsiu Wei

AU - Wang, Chien Yuan

PY - 2005/12

Y1 - 2005/12

N2 - FT-IR spectra of the co-adsorption of benzene and CO have been performed to identify the preferred adsorption sites of hydrogen and benzene on a Pt/SiO2 catalyst for hydrogenation of benzene. Results of CO adsorbed on atop sites on Pt/SiO2 includes: an α peak at 2091 cm -1, a β peak at 2080 cm-1 and a γ peak at 2067 cm-1 indicating three kinds of adsorption sites for dissociative hydrogen on Pt/SiO2. The site of lowest CO stretching frequency offers stronger adsorbates-metal interaction for benzene and hydrogen. Hydrogen binding on the site of lowest CO stretching frequency before benzene adsorption significantly enhances the reaction rate of benzene hydrogenation.

AB - FT-IR spectra of the co-adsorption of benzene and CO have been performed to identify the preferred adsorption sites of hydrogen and benzene on a Pt/SiO2 catalyst for hydrogenation of benzene. Results of CO adsorbed on atop sites on Pt/SiO2 includes: an α peak at 2091 cm -1, a β peak at 2080 cm-1 and a γ peak at 2067 cm-1 indicating three kinds of adsorption sites for dissociative hydrogen on Pt/SiO2. The site of lowest CO stretching frequency offers stronger adsorbates-metal interaction for benzene and hydrogen. Hydrogen binding on the site of lowest CO stretching frequency before benzene adsorption significantly enhances the reaction rate of benzene hydrogenation.

KW - Benzene hydrogenation

KW - CO adsorption

KW - FTIR

KW - Pt/SiO

UR - http://www.scopus.com/inward/record.url?scp=27844522374&partnerID=8YFLogxK

U2 - 10.1007/s10562-005-8684-7

DO - 10.1007/s10562-005-8684-7

M3 - 文章

AN - SCOPUS:27844522374

SN - 1011-372X

VL - 105

SP - 149

EP - 155

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Infrared study of benzene hydrogenation on Pt/SiO₂ catalyst by co-adsorption of CO and benzene

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this