Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C-H arylation strategy

Yi Kai Peng; Kun Mu Lee; Chang Chieh Ting; Ming Wei Hsu; Ching Yuan Liu

doi:10.1039/c9ta09777e

Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C-H arylation strategy

Yi Kai Peng
, Kun Mu Lee
, Chang Chieh Ting
, Ming Wei Hsu
, Ching Yuan Liu^*

^*Corresponding author for this work

Department of Chemical and Materials Engineering

National Central University

Research output: Contribution to journal › Journal Article › peer-review

25 Scopus citations

Abstract

Previously, benzotrithiophene (BTT)-based hole-transporting materials (HTMs) had to be doped with three chemical agents for high-efficiency perovskite solar cells (PSC). This work describes significant progress by which the first dopant-free BTT core-based HTM (YKP03) with EDOT spacers was readily accessed by step-saving direct C-H arylation. PSCs with dopant-free YKP03 showed promising efficiencies of up to 16.15% with potential long-term storage stability.

Original language	English
Pages (from-to)	24765-24770
Number of pages	6
Journal	Journal of Materials Chemistry A
Volume	7
Issue number	43
DOIs	https://doi.org/10.1039/c9ta09777e
State	Published - 2019

Bibliographical note

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

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title = "Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C-H arylation strategy",

abstract = "Previously, benzotrithiophene (BTT)-based hole-transporting materials (HTMs) had to be doped with three chemical agents for high-efficiency perovskite solar cells (PSC). This work describes significant progress by which the first dopant-free BTT core-based HTM (YKP03) with EDOT spacers was readily accessed by step-saving direct C-H arylation. PSCs with dopant-free YKP03 showed promising efficiencies of up to 16.15\% with potential long-term storage stability.",

author = "Peng, \{Yi Kai\} and Lee, \{Kun Mu\} and Ting, \{Chang Chieh\} and Hsu, \{Ming Wei\} and Liu, \{Ching Yuan\}",

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year = "2019",

doi = "10.1039/c9ta09777e",

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T2 - Step-saving installation of π-spacers by a direct C-H arylation strategy

AU - Peng, Yi Kai

AU - Lee, Kun Mu

AU - Ting, Chang Chieh

AU - Hsu, Ming Wei

AU - Liu, Ching Yuan

PY - 2019

Y1 - 2019

N2 - Previously, benzotrithiophene (BTT)-based hole-transporting materials (HTMs) had to be doped with three chemical agents for high-efficiency perovskite solar cells (PSC). This work describes significant progress by which the first dopant-free BTT core-based HTM (YKP03) with EDOT spacers was readily accessed by step-saving direct C-H arylation. PSCs with dopant-free YKP03 showed promising efficiencies of up to 16.15% with potential long-term storage stability.

AB - Previously, benzotrithiophene (BTT)-based hole-transporting materials (HTMs) had to be doped with three chemical agents for high-efficiency perovskite solar cells (PSC). This work describes significant progress by which the first dopant-free BTT core-based HTM (YKP03) with EDOT spacers was readily accessed by step-saving direct C-H arylation. PSCs with dopant-free YKP03 showed promising efficiencies of up to 16.15% with potential long-term storage stability.

UR - https://www.scopus.com/pages/publications/85074706612

U2 - 10.1039/c9ta09777e

DO - 10.1039/c9ta09777e

M3 - 文章

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JO - Journal of Materials Chemistry A

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IS - 43

ER -

Making benzotrithiophene derivatives dopant-free for perovskite solar cells: Step-saving installation of π-spacers by a direct C-H arylation strategy

Abstract

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