Microdomain-tailored crystallization kinetics of block copolymers

Hsin Lung Chen; Shu Ching Hsiao; Tsang Lang Lin; Kazuhiro Yamauchi; Hirokazu Hasegawa; Takeji Hashimoto

doi:10.1021/ma001485e

Microdomain-tailored crystallization kinetics of block copolymers

Hsin Lung Chen, Shu Ching Hsiao, Tsang Lang Lin, Kazuhiro Yamauchi, Hirokazu Hasegawa, Takeji Hashimoto

Research output: Contribution to journal › Journal Article › peer-review

174 Scopus citations

Abstract

The implementation of microdomain (MD) transformation to finely tailor the crystallization kinetics in a diblock copolymer was demonstrated. The basis for the parallel transition of crystallization kinetics with MD morphology was discussed using the direct proportionality between the nucleation rate and MD volume. It was shown that the poly(ethylene oxide)-blocks lamellar MDs becomes highly tortuous and interconnected after crystallization.

Original language	English
Pages (from-to)	671-674
Number of pages	4
Journal	Macromolecules
Volume	34
Issue number	4
DOIs	https://doi.org/10.1021/ma001485e
State	Published - 13 02 2001
Externally published	Yes

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title = "Microdomain-tailored crystallization kinetics of block copolymers",

abstract = "The implementation of microdomain (MD) transformation to finely tailor the crystallization kinetics in a diblock copolymer was demonstrated. The basis for the parallel transition of crystallization kinetics with MD morphology was discussed using the direct proportionality between the nucleation rate and MD volume. It was shown that the poly(ethylene oxide)-blocks lamellar MDs becomes highly tortuous and interconnected after crystallization.",

author = "Chen, {Hsin Lung} and Hsiao, {Shu Ching} and Lin, {Tsang Lang} and Kazuhiro Yamauchi and Hirokazu Hasegawa and Takeji Hashimoto",

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AU - Chen, Hsin Lung

AU - Hsiao, Shu Ching

AU - Lin, Tsang Lang

AU - Yamauchi, Kazuhiro

AU - Hasegawa, Hirokazu

AU - Hashimoto, Takeji

PY - 2001/2/13

Y1 - 2001/2/13

N2 - The implementation of microdomain (MD) transformation to finely tailor the crystallization kinetics in a diblock copolymer was demonstrated. The basis for the parallel transition of crystallization kinetics with MD morphology was discussed using the direct proportionality between the nucleation rate and MD volume. It was shown that the poly(ethylene oxide)-blocks lamellar MDs becomes highly tortuous and interconnected after crystallization.

AB - The implementation of microdomain (MD) transformation to finely tailor the crystallization kinetics in a diblock copolymer was demonstrated. The basis for the parallel transition of crystallization kinetics with MD morphology was discussed using the direct proportionality between the nucleation rate and MD volume. It was shown that the poly(ethylene oxide)-blocks lamellar MDs becomes highly tortuous and interconnected after crystallization.

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U2 - 10.1021/ma001485e

DO - 10.1021/ma001485e

M3 - 文章

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SP - 671

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JO - Macromolecules

JF - Macromolecules

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Microdomain-tailored crystallization kinetics of block copolymers

Abstract

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