Abstract
Cr-Ni alloy deposits with different chemical compositions could be obtained from a bath with trivalent Cr and divalent Ni ions. With a plating current density above 20A dm-2, amorphous Cr-rich alloy deposits were obtained, and crystalline Ni-rich deposits were achieved with an electroplating current density lower than 15 A dm-2. The hardness of the Ni-rich deposit decreased gradually with increasing flame-heating time. On the contrary, the hardness of Cr-rich alloy deposit could be significantly increased from 550Hv to 1450Hv after flame heating for 3s. The results of a microstructure study show that the precipitation of nano-sized carbon-related particles, possibly diamond-like particles, could be the main hardening mechanism of flame-heated Cr-rich alloy deposit. These particles have particularly high hardness values, and they distort the nearby Cr-rich lattice, which leads to obvious strain fields in the flame-hardened Cr-rich alloy deposits.
| Original language | English |
|---|---|
| Pages (from-to) | 325-329 |
| Number of pages | 5 |
| Journal | Surface and Coatings Technology |
| Volume | 206 |
| Issue number | 2-3 |
| DOIs | |
| State | Published - 25 10 2011 |
Keywords
- Cr-Ni alloy deposit
- Hardness
- Microstructure
- Trivalent chromium ions