New oxindole-bridged acceptors for organic sensitizers: Substitution and performance studies in dye-sensitized solar cells

Yogesh S. Tingare; Chaochin Su; Ming Tai Shen; Sheng Han Tsai; Shih Yu Ho; Wen Ren Li

doi:10.3390/molecules25092159

New oxindole-bridged acceptors for organic sensitizers: Substitution and performance studies in dye-sensitized solar cells

Yogesh S. Tingare^*, Chaochin Su, Ming Tai Shen, Sheng Han Tsai, Shih Yu Ho, Wen Ren Li

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

9 Scopus citations

Abstract

New D-π-A configured organic sensitizers featuring halogen-substituted oxindole-bridged acceptor units have been synthesized for dye-sensitized solar cells applications. Among fluorine, bromine, and iodine substitution, the cell based on bromine incorporated dye exhibited the highest efficiency. The oxindoles in these sensitizers were found to assist the electron injection through the chelation of their amide carbonyl groups to the TiO₂ surface. This study provides an alternate approach for future rational dye design to gain excellent DSSC performance.

Original language	English
Article number	2159
Journal	Molecules
Volume	25
Issue number	9
DOIs	https://doi.org/10.3390/molecules25092159
State	Published - 05 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 by the authors.

Keywords

Dye-sensitized solar cells
Electron injection
Halogens
Oxindoles

Access to Document

10.3390/molecules25092159

Cite this

@article{a255a69ee1bd4338a025d34e6744e05f,

title = "New oxindole-bridged acceptors for organic sensitizers: Substitution and performance studies in dye-sensitized solar cells",

abstract = "New D-π-A configured organic sensitizers featuring halogen-substituted oxindole-bridged acceptor units have been synthesized for dye-sensitized solar cells applications. Among fluorine, bromine, and iodine substitution, the cell based on bromine incorporated dye exhibited the highest efficiency. The oxindoles in these sensitizers were found to assist the electron injection through the chelation of their amide carbonyl groups to the TiO2 surface. This study provides an alternate approach for future rational dye design to gain excellent DSSC performance.",

keywords = "Dye-sensitized solar cells, Electron injection, Halogens, Oxindoles",

author = "Tingare, {Yogesh S.} and Chaochin Su and Shen, {Ming Tai} and Tsai, {Sheng Han} and Ho, {Shih Yu} and Li, {Wen Ren}",

note = "Publisher Copyright: {\textcopyright} 2020 by the authors.",

year = "2020",

month = may,

doi = "10.3390/molecules25092159",

language = "英语",

volume = "25",

journal = "Molecules",

issn = "1420-3049",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "9",

}

TY - JOUR

T1 - New oxindole-bridged acceptors for organic sensitizers

T2 - Substitution and performance studies in dye-sensitized solar cells

AU - Tingare, Yogesh S.

AU - Su, Chaochin

AU - Shen, Ming Tai

AU - Tsai, Sheng Han

AU - Ho, Shih Yu

AU - Li, Wen Ren

PY - 2020/5

Y1 - 2020/5

N2 - New D-π-A configured organic sensitizers featuring halogen-substituted oxindole-bridged acceptor units have been synthesized for dye-sensitized solar cells applications. Among fluorine, bromine, and iodine substitution, the cell based on bromine incorporated dye exhibited the highest efficiency. The oxindoles in these sensitizers were found to assist the electron injection through the chelation of their amide carbonyl groups to the TiO2 surface. This study provides an alternate approach for future rational dye design to gain excellent DSSC performance.

AB - New D-π-A configured organic sensitizers featuring halogen-substituted oxindole-bridged acceptor units have been synthesized for dye-sensitized solar cells applications. Among fluorine, bromine, and iodine substitution, the cell based on bromine incorporated dye exhibited the highest efficiency. The oxindoles in these sensitizers were found to assist the electron injection through the chelation of their amide carbonyl groups to the TiO2 surface. This study provides an alternate approach for future rational dye design to gain excellent DSSC performance.

KW - Dye-sensitized solar cells

KW - Electron injection

KW - Halogens

KW - Oxindoles

UR - http://www.scopus.com/inward/record.url?scp=85084382975&partnerID=8YFLogxK

U2 - 10.3390/molecules25092159

DO - 10.3390/molecules25092159

M3 - 文章

C2 - 32380749

AN - SCOPUS:85084382975

SN - 1420-3049

VL - 25

JO - Molecules

JF - Molecules

IS - 9

M1 - 2159

ER -

New oxindole-bridged acceptors for organic sensitizers: Substitution and performance studies in dye-sensitized solar cells

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this