Photoelectrochemical response for Cu-doped ZnIn2S4 electrode created using chemical bath deposition

Ya Cian Yu; Ming Zong Liou; Wei Che Li; Kong Wei Cheng

doi:10.1109/ICCCENG.2010.5560374

Photoelectrochemical response for Cu-doped ZnIn₂S₄ electrode created using chemical bath deposition

Ya Cian Yu^*
, Ming Zong Liou
, Wei Che Li
, Kong Wei Cheng

^*Corresponding author for this work

Department of Chemical and Materials Engineering

Chang Gung University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Polycrystalline Cu-doped ZnIn₂S₄ samples were grown on fluorine doped-tin-oxide-coated glass substrates using chemical bath deposition. The effect of [Cu]/[Cu+Zn] molar ratio in solution bath on the structural, optical and photoelectrochemical properties of the samples was investigated. From the results of X-ray diffraction (XRD) patterns of samples, a small shift in the peaks to a higher-angle was observed with the increase in Cu content in the film. The thicknesses and direct band gaps of the samples are in the ranges of 520-1260 nm and 2.51-2.09 eV, as obtained from surface profile measurement and transmittance/reflectance spectra, respectively. The highest photoelectrochemical response of samples was 1.15 mA/cm² at an external potential of + 1.0 V vs. an Ag/AgCl electrode in 0.5 M K ₂SO₄ solution under illumination using a 300W Xe lamp system with the light intensity set at 100 mW/cm².

Original language	English
Title of host publication	ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings
Pages	129-132
Number of pages	4
DOIs	https://doi.org/10.1109/ICCCENG.2010.5560374
State	Published - 2010
Event	2010 International Conference on Environmental and Agriculture Engineering, ICEAE 2010 - Kyoto, Japan Duration: 01 08 2010 → 03 08 2010

Publication series

Name	ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings

Conference

Conference	2010 International Conference on Environmental and Agriculture Engineering, ICEAE 2010
Country/Territory	Japan
City	Kyoto
Period	01/08/10 → 03/08/10

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Chemical synthesis
Photocatalyst
Thin film

Access to Document

10.1109/ICCCENG.2010.5560374

Cite this

Yu, Y. C., Liou, M. Z., Li, W. C., & Cheng, K. W. (2010). Photoelectrochemical response for Cu-doped ZnIn₂S₄ electrode created using chemical bath deposition. In ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings (pp. 129-132). Article 5560374 (ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings). https://doi.org/10.1109/ICCCENG.2010.5560374

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title = "Photoelectrochemical response for Cu-doped ZnIn2S4 electrode created using chemical bath deposition",

abstract = "Polycrystalline Cu-doped ZnIn2S4 samples were grown on fluorine doped-tin-oxide-coated glass substrates using chemical bath deposition. The effect of [Cu]/[Cu+Zn] molar ratio in solution bath on the structural, optical and photoelectrochemical properties of the samples was investigated. From the results of X-ray diffraction (XRD) patterns of samples, a small shift in the peaks to a higher-angle was observed with the increase in Cu content in the film. The thicknesses and direct band gaps of the samples are in the ranges of 520-1260 nm and 2.51-2.09 eV, as obtained from surface profile measurement and transmittance/reflectance spectra, respectively. The highest photoelectrochemical response of samples was 1.15 mA/cm2 at an external potential of + 1.0 V vs. an Ag/AgCl electrode in 0.5 M K 2SO4 solution under illumination using a 300W Xe lamp system with the light intensity set at 100 mW/cm2.",

keywords = "Chemical synthesis, Photocatalyst, Thin film",

author = "Yu, \{Ya Cian\} and Liou, \{Ming Zong\} and Li, \{Wei Che\} and Cheng, \{Kong Wei\}",

year = "2010",

doi = "10.1109/ICCCENG.2010.5560374",

language = "英语",

isbn = "9781424477647",

series = "ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings",

pages = "129--132",

booktitle = "ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings",

note = "2010 International Conference on Environmental and Agriculture Engineering, ICEAE 2010 ; Conference date: 01-08-2010 Through 03-08-2010",

}

Yu, YC, Liou, MZ, Li, WC & Cheng, KW 2010, Photoelectrochemical response for Cu-doped ZnIn₂S₄ electrode created using chemical bath deposition. in ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings., 5560374, ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings, pp. 129-132, 2010 International Conference on Environmental and Agriculture Engineering, ICEAE 2010, Kyoto, Japan, 01/08/10. https://doi.org/10.1109/ICCCENG.2010.5560374

Photoelectrochemical response for Cu-doped ZnIn₂S₄ electrode created using chemical bath deposition. / Yu, Ya Cian; Liou, Ming Zong; Li, Wei Che et al.
ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings. 2010. p. 129-132 5560374 (ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Photoelectrochemical response for Cu-doped ZnIn2S4 electrode created using chemical bath deposition

AU - Yu, Ya Cian

AU - Liou, Ming Zong

AU - Li, Wei Che

AU - Cheng, Kong Wei

PY - 2010

Y1 - 2010

N2 - Polycrystalline Cu-doped ZnIn2S4 samples were grown on fluorine doped-tin-oxide-coated glass substrates using chemical bath deposition. The effect of [Cu]/[Cu+Zn] molar ratio in solution bath on the structural, optical and photoelectrochemical properties of the samples was investigated. From the results of X-ray diffraction (XRD) patterns of samples, a small shift in the peaks to a higher-angle was observed with the increase in Cu content in the film. The thicknesses and direct band gaps of the samples are in the ranges of 520-1260 nm and 2.51-2.09 eV, as obtained from surface profile measurement and transmittance/reflectance spectra, respectively. The highest photoelectrochemical response of samples was 1.15 mA/cm2 at an external potential of + 1.0 V vs. an Ag/AgCl electrode in 0.5 M K 2SO4 solution under illumination using a 300W Xe lamp system with the light intensity set at 100 mW/cm2.

AB - Polycrystalline Cu-doped ZnIn2S4 samples were grown on fluorine doped-tin-oxide-coated glass substrates using chemical bath deposition. The effect of [Cu]/[Cu+Zn] molar ratio in solution bath on the structural, optical and photoelectrochemical properties of the samples was investigated. From the results of X-ray diffraction (XRD) patterns of samples, a small shift in the peaks to a higher-angle was observed with the increase in Cu content in the film. The thicknesses and direct band gaps of the samples are in the ranges of 520-1260 nm and 2.51-2.09 eV, as obtained from surface profile measurement and transmittance/reflectance spectra, respectively. The highest photoelectrochemical response of samples was 1.15 mA/cm2 at an external potential of + 1.0 V vs. an Ag/AgCl electrode in 0.5 M K 2SO4 solution under illumination using a 300W Xe lamp system with the light intensity set at 100 mW/cm2.

KW - Chemical synthesis

KW - Photocatalyst

KW - Thin film

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Yu YC, Liou MZ, Li WC, Cheng KW. Photoelectrochemical response for Cu-doped ZnIn₂S₄ electrode created using chemical bath deposition. In ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings. 2010. p. 129-132. 5560374. (ICCCE 2010 - 2010 International Conference on Chemistry and Chemical Engineering, Proceedings). doi: 10.1109/ICCCENG.2010.5560374