TY - JOUR
T1 - Selective localization of carbon nanotube and organoclay in biodegradable poly(butylene succinate)/polylactide blend-based nanocomposites with enhanced rigidity, toughness and electrical conductivity
AU - Sivanjineyulu, Veluri
AU - Behera, Kartik
AU - Chang, Yen Hsiang
AU - Chiu, Fang Chyou
N1 - Publisher Copyright:
© 2018 Elsevier Ltd
PY - 2018/11
Y1 - 2018/11
N2 - Carbon nanotube (CNT) and organo-montmorillonite (15A) were used individually and simultaneously as reinforcing fillers to fabricate poly(butylene succinate)/polylactide (PBS/PLA) blend-based nanocomposites. Poly(butylene succinate-co-lactate) served as compatibilizer for the PBS/PLA blend. Morphological results demonstrated that the added CNT was distributed mainly in the PBS matrix, whereas the added 15A was selectively localized within the dispersed PLA domains. Adding only 15A produced a quasi co-continuous PBS-PLA morphology. DSC results confirmed the nucleation effect of CNT on the crystallization of PBS and PLA, whereas 15A facilitated only the nucleation of PLA. The CNT exerted greater influence than 15A on the samples’ rheological properties. The Young's modulus and impact strength of the nanocomposites increased up to 4.2 and 2.8 times, respectively, compared with those of the blend. The electrical resistivity of the blend decreased by up to 11 orders at 3 phr CNT loading. The electrical-percolation threshold was constructed at 0.5 phr CNT loading.
AB - Carbon nanotube (CNT) and organo-montmorillonite (15A) were used individually and simultaneously as reinforcing fillers to fabricate poly(butylene succinate)/polylactide (PBS/PLA) blend-based nanocomposites. Poly(butylene succinate-co-lactate) served as compatibilizer for the PBS/PLA blend. Morphological results demonstrated that the added CNT was distributed mainly in the PBS matrix, whereas the added 15A was selectively localized within the dispersed PLA domains. Adding only 15A produced a quasi co-continuous PBS-PLA morphology. DSC results confirmed the nucleation effect of CNT on the crystallization of PBS and PLA, whereas 15A facilitated only the nucleation of PLA. The CNT exerted greater influence than 15A on the samples’ rheological properties. The Young's modulus and impact strength of the nanocomposites increased up to 4.2 and 2.8 times, respectively, compared with those of the blend. The electrical resistivity of the blend decreased by up to 11 orders at 3 phr CNT loading. The electrical-percolation threshold was constructed at 0.5 phr CNT loading.
KW - A. Nanocomposites
KW - B. Electrical properties
KW - B. Mechanical properties
KW - B. Thermal properties
UR - http://www.scopus.com/inward/record.url?scp=85051377411&partnerID=8YFLogxK
U2 - 10.1016/j.compositesa.2018.08.009
DO - 10.1016/j.compositesa.2018.08.009
M3 - 文章
AN - SCOPUS:85051377411
SN - 1359-835X
VL - 114
SP - 30
EP - 39
JO - Composites Part A: Applied Science and Manufacturing
JF - Composites Part A: Applied Science and Manufacturing
ER -