Structural design and characterization of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers

Kuo Hui Wu; Chih Wei Tsai; Wen Chien Huang; Wei Che Hung

doi:10.1016/j.mseb.2021.115088

Structural design and characterization of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers

Kuo Hui Wu^*, Chih Wei Tsai, Wen Chien Huang, Wei Che Hung

^*Corresponding author for this work

Research output: Contribution to journal › Journal Article › peer-review

7 Scopus citations

Abstract

Three types of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers, poly(adamantyl methacrylate-co-methyl methacrylate) [P(ADMA-co-MMA)], poly(tricyclodecyl methacrylate-co-methyl methacrylate) [P(TCDMA-co-MMA)] and poly(adamantyl methacrylate-co-tricyclodecyl methacrylate-co-methyl methacrylate) [P(ADMA-co-TCDMA-co-MMA)] were synthesized via the free-radical polymerization method. The effects of structural design on the thermal, mechanical, dielectric and optical properties of the synthesized copolymers were investigated. The results showed that the tricycloalkyl-containing methacrylate copolymers increased the thermal stability, mechanical strength and transparency in the UV–visible region as compared with PMMA. Additionally, a lower water absorption and dielectric constant were obtained. These results demonstrated that tricycloalkyl-containing methacrylate copolymers are promising candidates for use as high value-added optical plastics in microelectronics and optoelectronics applications.

Original language	English
Article number	115088
Journal	Materials Science and Engineering: B
Volume	267
DOIs	https://doi.org/10.1016/j.mseb.2021.115088
State	Published - 05 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 Elsevier B.V.

Keywords

Adamantane
C hydrocarbon resin
Poly(methyl methacrylate)
Tricyclodecane

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10.1016/j.mseb.2021.115088

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@article{07566b1fb7744f00af5b9cfcf3caee67,

title = "Structural design and characterization of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers",

abstract = "Three types of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers, poly(adamantyl methacrylate-co-methyl methacrylate) [P(ADMA-co-MMA)], poly(tricyclodecyl methacrylate-co-methyl methacrylate) [P(TCDMA-co-MMA)] and poly(adamantyl methacrylate-co-tricyclodecyl methacrylate-co-methyl methacrylate) [P(ADMA-co-TCDMA-co-MMA)] were synthesized via the free-radical polymerization method. The effects of structural design on the thermal, mechanical, dielectric and optical properties of the synthesized copolymers were investigated. The results showed that the tricycloalkyl-containing methacrylate copolymers increased the thermal stability, mechanical strength and transparency in the UV–visible region as compared with PMMA. Additionally, a lower water absorption and dielectric constant were obtained. These results demonstrated that tricycloalkyl-containing methacrylate copolymers are promising candidates for use as high value-added optical plastics in microelectronics and optoelectronics applications.",

keywords = "Adamantane, C hydrocarbon resin, Poly(methyl methacrylate), Tricyclodecane",

author = "Wu, {Kuo Hui} and Tsai, {Chih Wei} and Huang, {Wen Chien} and Hung, {Wei Che}",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

month = may,

doi = "10.1016/j.mseb.2021.115088",

language = "英语",

volume = "267",

journal = "Materials Science and Engineering: B",

issn = "0921-5107",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Structural design and characterization of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers

AU - Wu, Kuo Hui

AU - Tsai, Chih Wei

AU - Huang, Wen Chien

AU - Hung, Wei Che

PY - 2021/5

Y1 - 2021/5

N2 - Three types of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers, poly(adamantyl methacrylate-co-methyl methacrylate) [P(ADMA-co-MMA)], poly(tricyclodecyl methacrylate-co-methyl methacrylate) [P(TCDMA-co-MMA)] and poly(adamantyl methacrylate-co-tricyclodecyl methacrylate-co-methyl methacrylate) [P(ADMA-co-TCDMA-co-MMA)] were synthesized via the free-radical polymerization method. The effects of structural design on the thermal, mechanical, dielectric and optical properties of the synthesized copolymers were investigated. The results showed that the tricycloalkyl-containing methacrylate copolymers increased the thermal stability, mechanical strength and transparency in the UV–visible region as compared with PMMA. Additionally, a lower water absorption and dielectric constant were obtained. These results demonstrated that tricycloalkyl-containing methacrylate copolymers are promising candidates for use as high value-added optical plastics in microelectronics and optoelectronics applications.

AB - Three types of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers, poly(adamantyl methacrylate-co-methyl methacrylate) [P(ADMA-co-MMA)], poly(tricyclodecyl methacrylate-co-methyl methacrylate) [P(TCDMA-co-MMA)] and poly(adamantyl methacrylate-co-tricyclodecyl methacrylate-co-methyl methacrylate) [P(ADMA-co-TCDMA-co-MMA)] were synthesized via the free-radical polymerization method. The effects of structural design on the thermal, mechanical, dielectric and optical properties of the synthesized copolymers were investigated. The results showed that the tricycloalkyl-containing methacrylate copolymers increased the thermal stability, mechanical strength and transparency in the UV–visible region as compared with PMMA. Additionally, a lower water absorption and dielectric constant were obtained. These results demonstrated that tricycloalkyl-containing methacrylate copolymers are promising candidates for use as high value-added optical plastics in microelectronics and optoelectronics applications.

KW - Adamantane

KW - C hydrocarbon resin

KW - Poly(methyl methacrylate)

KW - Tricyclodecane

UR - http://www.scopus.com/inward/record.url?scp=85101486228&partnerID=8YFLogxK

U2 - 10.1016/j.mseb.2021.115088

DO - 10.1016/j.mseb.2021.115088

M3 - 文章

AN - SCOPUS:85101486228

SN - 0921-5107

VL - 267

JO - Materials Science and Engineering: B

JF - Materials Science and Engineering: B

M1 - 115088

ER -

Structural design and characterization of tricycloalkyl-containing methacrylate with methyl methacrylate copolymers

Abstract

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Keywords

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