TY - JOUR
T1 - Surface-enhanced Raman scattering (SERS)-based volatile organic compounds (VOCs) detection using plasmonic bimetallic nanogap substrate
AU - Wong, Chi Lok
AU - Dinish, U. S.
AU - Buddharaju, Kavitha Devi
AU - Schmidt, Michael Stenbæk
AU - Olivo, Malini
N1 - Publisher Copyright:
© 2014, Springer-Verlag Berlin Heidelberg.
PY - 2014/10/9
Y1 - 2014/10/9
N2 - In this paper, we present surface-enhanced Raman scattering (SERS)-based volatile organic compounds (VOCs) detection with bimetallic nanogap structure substrate. Deep UV photolithography at the wavelength of 250 nm is used to pattern circular shape nanostructures. The nanogap between adjacent circular patterns is 30 ± 5 nm. Silver (30 nm) and gold (15 nm) plasmonic active layers are deposited on the nanostructures subsequently. SERS measurements on different concentrations of acetone vapor ranged from 0.7, 1.5, 3.5, 10.3, 24.5 % and control have been performed with the substrate. The measurement results are found reproducible, and the detection limit is found to be 9.5 pg (acetone molecule). The detection sensitivity is 28.7 % higher than that of the recent reported leaning silicon nanopillar substrate. With further system miniaturization, the sensing technique can work as a portable SERS-based VOCs detection platform for point-of-care breath analysis, homeland security, chemical sensing and environmental monitoring.
AB - In this paper, we present surface-enhanced Raman scattering (SERS)-based volatile organic compounds (VOCs) detection with bimetallic nanogap structure substrate. Deep UV photolithography at the wavelength of 250 nm is used to pattern circular shape nanostructures. The nanogap between adjacent circular patterns is 30 ± 5 nm. Silver (30 nm) and gold (15 nm) plasmonic active layers are deposited on the nanostructures subsequently. SERS measurements on different concentrations of acetone vapor ranged from 0.7, 1.5, 3.5, 10.3, 24.5 % and control have been performed with the substrate. The measurement results are found reproducible, and the detection limit is found to be 9.5 pg (acetone molecule). The detection sensitivity is 28.7 % higher than that of the recent reported leaning silicon nanopillar substrate. With further system miniaturization, the sensing technique can work as a portable SERS-based VOCs detection platform for point-of-care breath analysis, homeland security, chemical sensing and environmental monitoring.
UR - https://www.scopus.com/pages/publications/85028119333
U2 - 10.1007/s00339-014-8723-6
DO - 10.1007/s00339-014-8723-6
M3 - 文章
AN - SCOPUS:85028119333
SN - 0947-8396
VL - 117
SP - 687
EP - 692
JO - Applied Physics A: Materials Science and Processing
JF - Applied Physics A: Materials Science and Processing
IS - 2
ER -