TY - JOUR
T1 - Synthesis of perovskite-type potassium niobate using deep eutectic solvents
T2 - A promising electrode material for detection of bisphenol A
AU - Priya, Thangavelu Sakthi
AU - Chen, Tse Wei
AU - Chen, Shen Ming
AU - Kokulnathan, Thangavelu
AU - Lou, Bih Show
AU - Al-onazi, Wedad A.
AU - Al-Mohaimeed, Amal M.
AU - Elshikh, Mohamed S.
AU - Yu, Jaysan
N1 - Copyright © 2023 Elsevier Ltd. All rights reserved.
PY - 2023/3
Y1 - 2023/3
N2 - This study demonstrates a hydrothermal method to prepare perovskite-type potassium niobate (KNbO3) through deep eutectic solvent (DES), which is further used as an electrode material for the determination of bisphenol A (BPA). The as-synthesized KNbO3 was systematically characterized by different microscopic and spectroscopic techniques. The KNbO3-modified electrode demonstrates excellent electrocatalytic activity for BPA compared to the pristine electrode. The enhanced performance of the proposed sensor is attributed to the numerous active sites, large electrochemical surface area, high electrical conductivity, and rapid electron transfer. The fabricated sensor shows a wide detection range (0.01–84.3 μM), a low limit of detection (0.003 μM), a high sensitivity (0.51 μA μM−1 cm−2), and good anti-interference abilities towards the BPA detection by linear sweep voltammetry method. Besides, it was successfully applied to determining BPA in food samples, demonstrating good practicability. This design paves a new way to fabricate efficient electrode material for various electrochemical applications using a DES medium.
AB - This study demonstrates a hydrothermal method to prepare perovskite-type potassium niobate (KNbO3) through deep eutectic solvent (DES), which is further used as an electrode material for the determination of bisphenol A (BPA). The as-synthesized KNbO3 was systematically characterized by different microscopic and spectroscopic techniques. The KNbO3-modified electrode demonstrates excellent electrocatalytic activity for BPA compared to the pristine electrode. The enhanced performance of the proposed sensor is attributed to the numerous active sites, large electrochemical surface area, high electrical conductivity, and rapid electron transfer. The fabricated sensor shows a wide detection range (0.01–84.3 μM), a low limit of detection (0.003 μM), a high sensitivity (0.51 μA μM−1 cm−2), and good anti-interference abilities towards the BPA detection by linear sweep voltammetry method. Besides, it was successfully applied to determining BPA in food samples, demonstrating good practicability. This design paves a new way to fabricate efficient electrode material for various electrochemical applications using a DES medium.
KW - Alkali niobates
KW - Deep eutectic solvent
KW - Electrode material
KW - Food samples
KW - Electrodes
KW - Deep Eutectic Solvents
KW - Electrochemical Techniques/methods
UR - http://www.scopus.com/inward/record.url?scp=85147834274&partnerID=8YFLogxK
U2 - 10.1016/j.chemosphere.2023.137948
DO - 10.1016/j.chemosphere.2023.137948
M3 - 文章
C2 - 36716937
AN - SCOPUS:85147834274
SN - 0045-6535
VL - 318
SP - 137948
JO - Chemosphere
JF - Chemosphere
M1 - 137948
ER -
