Thermosensitive Polyacrylonitrile/Polyethylene Oxide/Polyacrylonitrile Membrane Separators for Prompt and Safer Thermal Lithium-Ion Battery Shutdown

With the rapid development of high-power and high-energy density lithium-ion batteries, thermal safety has become a critical issue. Due to the fast microstructure change triggered by heat, thermosensitive polymers have aroused increasing attention as thermal shutdown material candidates to prevent the thermal runaway of lithium-ion batteries. In this work, a sandwich-structured polyacrylonitrile/polyethylene oxide/polyacrylonitrile (PAN/PEO/PAN) fibrous membrane with prompt thermal shutdown properties and high thermal stability is prepared using electrospinning technique. The inner layer of the fusible PEO fibrous membrane impart the composite separator with a prompt thermal shutdown function at 80 °C. Meanwhile, the outer layer of the heat-resistant PAN membrane remains thermally stable, even at 200 °C. The large buffering temperature difference (120 °C) between the thermal shutdown temperature and the thermally stable temperature of the composite separator is wider than most of the reported separators and effectively enhances the thermal safety of the lithium-ion batteries. In addition, the PAN/PEO/PAN separator exhibits a higher porosity, better electrolyte wettability, larger ionic conductivity, and lower interfacial resistance compared with a commercial polypropylene/polyethylene/polypropylene (PP/PE/PP) separator. Moreover, the coin cells assembled by the PAN/PEO/PAN separator presents stable cycle performance and excellent rate capability. Therefore, the novel PAN/PEO/PAN membrane shows great potential as a promising candidate for much safer lithium-ion battery separators.