Treatment of complexed copper(II) solutions with electrochemical membrane processes

Ruey Shin Juang; Li Chun Lin

doi:10.1016/S0043-1354(99)00112-8

Treatment of complexed copper(II) solutions with electrochemical membrane processes

Ruey Shin Juang^*, Li Chun Lin

^*Corresponding author for this work

Yuan Ze University

Research output: Contribution to journal › Journal Article › peer-review

36 Scopus citations

Abstract

An electrochemical membrane process was used to treat complexed Cu(II) solutions of citric acid, nitrilotriacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA). An equimolar solution of Cu(II) and complexing agent was focused. The iridium oxide (IrO₂/Ti) and Pt (Pt/Ti) coated on titanium were used as anode and cathode, respectively. The cation exchange membrane Neosepta CM-1 was adopted. Experiments were carried out at different current densities (18.5-139 A/m²), initial catholyte pH (1-9) and Cu(II) concentrations (0.01-0.08 M), and initial anolyte NaNO₃ concentrations (0.001-0.2 M). An economically feasible current efficiency and recovery percentages of metals and complexing agents could be achieved if the concentration of the complexed Cu(II) was sufficiently high.

Original language	English
Pages (from-to)	43-50
Number of pages	8
Journal	Water Research
Volume	34
Issue number	1
DOIs	https://doi.org/10.1016/S0043-1354(99)00112-8
State	Published - 01 01 2000
Externally published	Yes

Keywords

Citrate
Copper
EDTA
Electrochemical membrane process
NTA
Simultaneous recovery

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10.1016/S0043-1354(99)00112-8

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title = "Treatment of complexed copper(II) solutions with electrochemical membrane processes",

abstract = "An electrochemical membrane process was used to treat complexed Cu(II) solutions of citric acid, nitrilotriacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA). An equimolar solution of Cu(II) and complexing agent was focused. The iridium oxide (IrO2/Ti) and Pt (Pt/Ti) coated on titanium were used as anode and cathode, respectively. The cation exchange membrane Neosepta CM-1 was adopted. Experiments were carried out at different current densities (18.5-139 A/m2), initial catholyte pH (1-9) and Cu(II) concentrations (0.01-0.08 M), and initial anolyte NaNO3 concentrations (0.001-0.2 M). An economically feasible current efficiency and recovery percentages of metals and complexing agents could be achieved if the concentration of the complexed Cu(II) was sufficiently high.",

keywords = "Citrate, Copper, EDTA, Electrochemical membrane process, NTA, Simultaneous recovery",

author = "Juang, {Ruey Shin} and Lin, {Li Chun}",

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T1 - Treatment of complexed copper(II) solutions with electrochemical membrane processes

AU - Juang, Ruey Shin

AU - Lin, Li Chun

PY - 2000/1/1

Y1 - 2000/1/1

N2 - An electrochemical membrane process was used to treat complexed Cu(II) solutions of citric acid, nitrilotriacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA). An equimolar solution of Cu(II) and complexing agent was focused. The iridium oxide (IrO2/Ti) and Pt (Pt/Ti) coated on titanium were used as anode and cathode, respectively. The cation exchange membrane Neosepta CM-1 was adopted. Experiments were carried out at different current densities (18.5-139 A/m2), initial catholyte pH (1-9) and Cu(II) concentrations (0.01-0.08 M), and initial anolyte NaNO3 concentrations (0.001-0.2 M). An economically feasible current efficiency and recovery percentages of metals and complexing agents could be achieved if the concentration of the complexed Cu(II) was sufficiently high.

AB - An electrochemical membrane process was used to treat complexed Cu(II) solutions of citric acid, nitrilotriacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA). An equimolar solution of Cu(II) and complexing agent was focused. The iridium oxide (IrO2/Ti) and Pt (Pt/Ti) coated on titanium were used as anode and cathode, respectively. The cation exchange membrane Neosepta CM-1 was adopted. Experiments were carried out at different current densities (18.5-139 A/m2), initial catholyte pH (1-9) and Cu(II) concentrations (0.01-0.08 M), and initial anolyte NaNO3 concentrations (0.001-0.2 M). An economically feasible current efficiency and recovery percentages of metals and complexing agents could be achieved if the concentration of the complexed Cu(II) was sufficiently high.

KW - Citrate

KW - Copper

KW - EDTA

KW - Electrochemical membrane process

KW - NTA

KW - Simultaneous recovery

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DO - 10.1016/S0043-1354(99)00112-8

M3 - 文章

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SN - 0043-1354

VL - 34

SP - 43

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JO - Water Research

JF - Water Research

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ER -

Treatment of complexed copper(II) solutions with electrochemical membrane processes

Abstract

Keywords

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