Vertical 2D/3D Heterojunction of Tin Perovskites for Highly Efficient HTM-Free Perovskite Solar Cell

Jin Tai Lin; Tzu Chi Chu; Deng Gao Chen; Zhi Xuan Huang; Hsiao Chien Chen; Chia Shuo Li; Chih I. Wu; Pi Tai Chou; Ching Wen Chiu; Hao Ming Chen

doi:10.1021/acsaem.0c02451

Vertical 2D/3D Heterojunction of Tin Perovskites for Highly Efficient HTM-Free Perovskite Solar Cell

Jin Tai Lin
, Tzu Chi Chu
, Deng Gao Chen
, Zhi Xuan Huang
, Hsiao Chien Chen
, Chia Shuo Li
, Chih I. Wu
, Pi Tai Chou^*
, Ching Wen Chiu^*
, Hao Ming Chen^*

^*Corresponding author for this work

Centre for Reliability Science and Technology

National Taiwan University

Research output: Contribution to journal › Journal Article › peer-review

29 Scopus citations

Abstract

Tin perovskite solar cells (PSCs) have been attracting attention in photovoltaic application, while the performance of Sn PSCs, especially for hole-transporting materials (HTMs)-free configuration, is relatively poor because of short mean-free-path for photogenerated charge carriers. We report a p-n junction with spatially appropriate architecture and energetic alignment in perovskite light-absorbing layer, resulting in an excellent performance of HTM-free Sn PSCs with a power conversion efficiency (PCE) of 5.17%, the highest value reported in HTM-free Sn PSCs. The p-n junction configuration plays a key role in achieving high efficiency and realizing excellent stability for more than 200 h operation.

Original language	English
Pages (from-to)	2041-2048
Number of pages	8
Journal	ACS Applied Energy Materials
Volume	4
Issue number	3
DOIs	https://doi.org/10.1021/acsaem.0c02451
State	Published - 22 03 2021

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UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

HTM-free
heterojunction
lead-free
perovskite
solar cell

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10.1021/acsaem.0c02451

Cite this

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title = "Vertical 2D/3D Heterojunction of Tin Perovskites for Highly Efficient HTM-Free Perovskite Solar Cell",

abstract = "Tin perovskite solar cells (PSCs) have been attracting attention in photovoltaic application, while the performance of Sn PSCs, especially for hole-transporting materials (HTMs)-free configuration, is relatively poor because of short mean-free-path for photogenerated charge carriers. We report a p-n junction with spatially appropriate architecture and energetic alignment in perovskite light-absorbing layer, resulting in an excellent performance of HTM-free Sn PSCs with a power conversion efficiency (PCE) of 5.17\%, the highest value reported in HTM-free Sn PSCs. The p-n junction configuration plays a key role in achieving high efficiency and realizing excellent stability for more than 200 h operation.",

keywords = "HTM-free, heterojunction, lead-free, perovskite, solar cell",

author = "Lin, \{Jin Tai\} and Chu, \{Tzu Chi\} and Chen, \{Deng Gao\} and Huang, \{Zhi Xuan\} and Chen, \{Hsiao Chien\} and Li, \{Chia Shuo\} and Wu, \{Chih I.\} and Chou, \{Pi Tai\} and Chiu, \{Ching Wen\} and Chen, \{Hao Ming\}",

note = "Publisher Copyright: {\textcopyright} ",

year = "2021",

month = mar,

day = "22",

doi = "10.1021/acsaem.0c02451",

language = "英语",

volume = "4",

pages = "2041--2048",

journal = "ACS Applied Energy Materials",

issn = "2574-0962",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Vertical 2D/3D Heterojunction of Tin Perovskites for Highly Efficient HTM-Free Perovskite Solar Cell

AU - Lin, Jin Tai

AU - Chu, Tzu Chi

AU - Chen, Deng Gao

AU - Huang, Zhi Xuan

AU - Chen, Hsiao Chien

AU - Li, Chia Shuo

AU - Wu, Chih I.

AU - Chou, Pi Tai

AU - Chiu, Ching Wen

AU - Chen, Hao Ming

PY - 2021/3/22

Y1 - 2021/3/22

N2 - Tin perovskite solar cells (PSCs) have been attracting attention in photovoltaic application, while the performance of Sn PSCs, especially for hole-transporting materials (HTMs)-free configuration, is relatively poor because of short mean-free-path for photogenerated charge carriers. We report a p-n junction with spatially appropriate architecture and energetic alignment in perovskite light-absorbing layer, resulting in an excellent performance of HTM-free Sn PSCs with a power conversion efficiency (PCE) of 5.17%, the highest value reported in HTM-free Sn PSCs. The p-n junction configuration plays a key role in achieving high efficiency and realizing excellent stability for more than 200 h operation.

AB - Tin perovskite solar cells (PSCs) have been attracting attention in photovoltaic application, while the performance of Sn PSCs, especially for hole-transporting materials (HTMs)-free configuration, is relatively poor because of short mean-free-path for photogenerated charge carriers. We report a p-n junction with spatially appropriate architecture and energetic alignment in perovskite light-absorbing layer, resulting in an excellent performance of HTM-free Sn PSCs with a power conversion efficiency (PCE) of 5.17%, the highest value reported in HTM-free Sn PSCs. The p-n junction configuration plays a key role in achieving high efficiency and realizing excellent stability for more than 200 h operation.

KW - HTM-free

KW - heterojunction

KW - lead-free

KW - perovskite

KW - solar cell

UR - https://www.scopus.com/pages/publications/85101664082

U2 - 10.1021/acsaem.0c02451

DO - 10.1021/acsaem.0c02451

M3 - 文章

AN - SCOPUS:85101664082

SN - 2574-0962

VL - 4

SP - 2041

EP - 2048

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 3

ER -

Vertical 2D/3D Heterojunction of Tin Perovskites for Highly Efficient HTM-Free Perovskite Solar Cell

Abstract

Bibliographical note

UN SDGs

Keywords

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