TY - JOUR
T1 - Mass-production of ZnO nanoparticles by precipitation in a rotating packed bed
T2 - effect of zinc salt
AU - Lin, Chia Chang
AU - You, Yi Cheng
N1 - Publisher Copyright:
© 2020 The Author(s)
PY - 2020/7/1
Y1 - 2020/7/1
N2 - The effect of three zinc salts (Zn(CH3COO)2, ZnSO4, and Zn(NO3)2) on the size of the precursors of the ZnO nanoparticles that were mass-produced by precipitation in a rotating packed bed was studied. The precursors were formed at a rotational speed of 2000 rpm and flow rates of 0.5 L/min by precipitation using various zinc salts and NaOH as the precipitant. When zinc salts were Zn(CH3COO)2 and ZnSO4, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/2. However, when the zinc salt was Zn(NO3)2, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/1. Additionally, various zinc salts yielded different effects of the concentrations of Zn2+ and OH− on the size of the precursors. Experimental results indicate that the smallest precursors for various zinc salts were obtained at a Zn(CH3COO)2 concentration of 0.4 mol/L and an NaOH concentration of 0.8 mol/L, a ZnSO4 concentration of 0.1 mol/L and an NaOH concentration of 0.2 mol/L, and a Zn(NO3)2 concentration of 0.2 mol/L and an NaOH concentration of 0.2 mol/L. ZnO nanoparticles were mass-produced by calcining these precursors at sufficient temperatures for 1 h. In this way, the average sizes of the ZnO nanoparticles that were mass-produced using Zn(NO3)2, Zn(CH3COO)2, and ZnSO4 as zinc salts were 98, 136, and 186 nm, respectively.
AB - The effect of three zinc salts (Zn(CH3COO)2, ZnSO4, and Zn(NO3)2) on the size of the precursors of the ZnO nanoparticles that were mass-produced by precipitation in a rotating packed bed was studied. The precursors were formed at a rotational speed of 2000 rpm and flow rates of 0.5 L/min by precipitation using various zinc salts and NaOH as the precipitant. When zinc salts were Zn(CH3COO)2 and ZnSO4, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/2. However, when the zinc salt was Zn(NO3)2, the smallest precursors were obtained at a Zn2+/OH− molar ratio of 1/1. Additionally, various zinc salts yielded different effects of the concentrations of Zn2+ and OH− on the size of the precursors. Experimental results indicate that the smallest precursors for various zinc salts were obtained at a Zn(CH3COO)2 concentration of 0.4 mol/L and an NaOH concentration of 0.8 mol/L, a ZnSO4 concentration of 0.1 mol/L and an NaOH concentration of 0.2 mol/L, and a Zn(NO3)2 concentration of 0.2 mol/L and an NaOH concentration of 0.2 mol/L. ZnO nanoparticles were mass-produced by calcining these precursors at sufficient temperatures for 1 h. In this way, the average sizes of the ZnO nanoparticles that were mass-produced using Zn(NO3)2, Zn(CH3COO)2, and ZnSO4 as zinc salts were 98, 136, and 186 nm, respectively.
KW - Mass-production
KW - Nanoparticles
KW - Precipitation
KW - Rotating packed bed
KW - ZnO
UR - http://www.scopus.com/inward/record.url?scp=85111017292&partnerID=8YFLogxK
U2 - 10.1016/j.jmrt.2020.05.040
DO - 10.1016/j.jmrt.2020.05.040
M3 - 文章
AN - SCOPUS:85111017292
SN - 2238-7854
VL - 9
SP - 8451
EP - 8458
JO - Journal of Materials Research and Technology
JF - Journal of Materials Research and Technology
IS - 4
ER -