Resolution of non-protein amino acids via Carica papaya lipase-catalyzed enantioselective transesterification

Toshifumi Miyazawa; Kazuki Onishi; Takashi Murashima; Takashi Yamada; Shau Wei Tsai

doi:10.1016/j.tetasy.2005.06.037

Resolution of non-protein amino acids via Carica papaya lipase-catalyzed enantioselective transesterification

Toshifumi Miyazawa^*
, Kazuki Onishi
, Takashi Murashima
, Takashi Yamada
, Shau Wei Tsai

^*此作品的通信作者

Konan University
National Cheng Kung University

研究成果: 期刊稿件 › 文章 › 同行評審

19 引文斯高帕斯（Scopus）

摘要

Carica papaya lipase-catalyzed transesterification of the 2,2,2-trifluoroethyl esters of N-benzyloxycarbonylated dl-amino acids carrying aliphatic side chains proceeded smoothly and, in almost all the cases, enantiospecifically (E = >200), affording the l-methyl esters and leaving the d-trifluoroethyl esters intact.

原文	英語
頁（從 - 到）	2569-2573
頁數	5
期刊	Tetrahedron Asymmetry
卷	16
發行號	15
DOIs	https://doi.org/10.1016/j.tetasy.2005.06.037
出版狀態	已出版 - 01 08 2005
對外發佈	是

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10.1016/j.tetasy.2005.06.037

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abstract = "Carica papaya lipase-catalyzed transesterification of the 2,2,2-trifluoroethyl esters of N-benzyloxycarbonylated dl-amino acids carrying aliphatic side chains proceeded smoothly and, in almost all the cases, enantiospecifically (E = >200), affording the l-methyl esters and leaving the d-trifluoroethyl esters intact.",

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AU - Miyazawa, Toshifumi

AU - Onishi, Kazuki

AU - Murashima, Takashi

AU - Yamada, Takashi

AU - Tsai, Shau Wei

PY - 2005/8/1

Y1 - 2005/8/1

N2 - Carica papaya lipase-catalyzed transesterification of the 2,2,2-trifluoroethyl esters of N-benzyloxycarbonylated dl-amino acids carrying aliphatic side chains proceeded smoothly and, in almost all the cases, enantiospecifically (E = >200), affording the l-methyl esters and leaving the d-trifluoroethyl esters intact.

AB - Carica papaya lipase-catalyzed transesterification of the 2,2,2-trifluoroethyl esters of N-benzyloxycarbonylated dl-amino acids carrying aliphatic side chains proceeded smoothly and, in almost all the cases, enantiospecifically (E = >200), affording the l-methyl esters and leaving the d-trifluoroethyl esters intact.

UR - https://www.scopus.com/pages/publications/23644454974

U2 - 10.1016/j.tetasy.2005.06.037

DO - 10.1016/j.tetasy.2005.06.037

M3 - 文章

AN - SCOPUS:23644454974

SN - 0957-4166

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ER -

Resolution of non-protein amino acids via Carica papaya lipase-catalyzed enantioselective transesterification

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