Synthesis of novel Type-II MnNb2O6/g-C3N4 Mott-Schottky heterojunction photocatalyst: Excellent photocatalytic performance and degradation mechanism of fluoroquinolone-based antibiotics

Naveed Ahmad, Chung Feng Jeffrey Kuo*, Mujahid Mustaqeem, Arumugam Sangili, Chih Ching Huang, Huan Tsung Chang

*此作品的通信作者

研究成果: 期刊稿件文章同行評審

46 引文 斯高帕斯(Scopus)

摘要

Fluoroquinolone antibiotics have been encountered in aquatic environments in quantities giving rise to significant concern recently. To cope with this problem, it is necessary to design a semiconductor photocatalyst having excellent photocatalytic efficiency to eliminate the antibiotics. The heterojunction is a likely situate where the efficiency of relevant photocatalyst can be strengthened. In this study, the performance of MnNb2O6/g-C3N4 (MNO/g-CN) composites in the photocatalytic degradation of ciprofloxacin (CIP) and tetracycline-HCl (TCH) antibiotics was explored. Enhanced photocatalytic activity of MNO/g-CN was found to be owing to electron's shifting between the MNO, and g-CN sheets, which promotes the formation of photo-generated e⁻/h⁺ pairs. This shows a low-waste, high-performance material exists to eradicate CIP and TCH from wastewater. Further, the structural, photochemical and light interacted properties of the MNO/g-CN photocatalyst, prepared by solvothermal method and sonication, were described using photochemical, physiochemical and electrochemical approaches. The synthesized photocatalyst owes its particular efficiency to its methodical photo-degradation of CIP and TC using visible light. The optimum composite 15% MNO/g-CN evinced the greatest photocatalytic efficiency with CIP and TCH photo-degradation of 94.10%, and 98.50%, respectively, and degradation mechanism were investigated using LC-MS spectroscopy. The suitable photocatalytic activity is ascribed to lower the recombination's rate of e⁻/h⁺ pairs. The scavenging evaluations proved that the h+ and O2 were two major photoactive species accomplishing the CIP and TCH photodegradation over MNO/g-CN under visible region. Our findings pave the way for the construction of efficient binary photocatalysts for antibiotic restitution.

原文英語
文章編號138027
頁(從 - 到)138027 - 138133
期刊Chemosphere
321
DOIs
出版狀態已出版 - 04 2023
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