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The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3-F⋯Osp3 interaction from polyfluorinated: trans -dihalo-palladium(ii) di-substituted pyridine complexes

  • Vijayanath Elakkat
  • , Chu Chun Chang
  • , Jun Yu Chen
  • , Yung Cheng Fang
  • , Chia Rui Shen*
  • , Ling Kung Liu
  • , Norman Lu
  • *此作品的通信作者
  • National Taipei University of Technology
  • Chang Gung Memorial Hospital
  • Academia Sinica - Institute of Chemistry

研究成果: 期刊稿件文章同行評審

22 引文 斯高帕斯(Scopus)

摘要

The first two examples of halogen bonding in the Csp3-F⋯Osp3 interaction have been both experimentally and theoretically proved for trans-[PdX2(3-HCF2CF2CH2OCH2py)2] complexes where X = Cl and Br. Both metal complexes with a Csp3-F⋯Osp3 halogen bond have a σ hole donating fluorine.

原文英語
頁(從 - 到)14259-14262
頁數4
期刊Chemical Communications
55
發行號95
DOIs
出版狀態已出版 - 2019
對外發佈

文獻附註

Publisher Copyright:
This journal is © The Royal Society of Chemistry.

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